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Merck

935972

Sodium hexafluorophosphate solution

in ethylene carbonate, dimethylcarbonate, and ethylmethylcarbonate, 1.0 M NaPF6 in EC/DMC/EMC=1:1:1 (v/v/v), battery grade

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Synonym(s):

1.0 M NaPF6 in EC/DMC/EMC

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About This Item

CAS Number:
MDL number:
NACRES:
MA.24
UNSPSC Code:
26111700
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grade

battery grade

Quality Segment

form

solution

sustainability

Sustainability features

concentration

0.95-1.10 M (NaPF6)

impurities

≤100 ppm Acid, ≤100.0 ppm H2O

application(s)

battery manufacturing

greener alternative category

SMILES string

[Na+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.Na/c1-7(2,3,4,5)6;/q-1;+1

InChI key

KMADQUOCJBLXRP-UHFFFAOYSA-N

General description

Sodium hexafluorophosphate (NaPF6) solution in ethylene carbonate (EC), dimethylcarbonate (DMC), and ethylmethylcarbonate (EMC) is a clear solution of battery grade sodium hexafluorophosphate dissolved in a a ternary mixture of EC/DMC/EMC (1:1:1) (v/v/v). We offer this with a superior quality suitable for battery research with low water and acid impurities.
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Application

The main application of 1.0 M NaPF6 in EC/DMC/EMC=1:1:1 (v/v/v) is as an electrolyte in sodium-ion batteries (NIBs). The solvent blend has a high dielectric constant, which allows for effective dissolution of the electrolyte salt and results in high ionic conductivity. The fraction of ethylene carbonate (EC) helps to form a stable, conductive solid electrolyte interphase (SEI) with many cathode anode materials. Ethyl methyl carbonate (EMC) and dimethyl carbonate (DMC) have lower viscosities and melting points than EC, and when mixed with EC result in an electrolyte with a good balance between desirable electrochemical properties, high dielectric constant, and low viscosity. This electrolyte has been shown to have good electrochemical performance even at low temperatures, making it suitable for use in cold environments.


Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 2 Oral

Target Organs

Kidney

Storage Class

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

77.0 °F

Flash Point (°C)

25 °C



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