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Merck

1.02521

Sodium hexanitrocobaltate(III)

[sodium cobalt(III)nitrite] for analysis EMSURE® ACS,Reag. Ph Eur

Synonym(s):

Sodium hexanitrocobaltate(III), Cobalt(III) sodium nitrite, Sodium cobaltinitrite

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About This Item

Linear Formula:
Na3[Co(NO2)6]
CAS Number:
Molecular Weight:
403.94
UNSPSC Code:
12352302
EC Index Number:
237-077-7
NACRES:
NA.21
MDL number:
Grade:
ACS reagent
Form:
powder
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grade

ACS reagent

Quality Segment

agency

reag. Ph. Eur.

product line

EMSURE®

form

powder

impurities

≤0.02% Insoluble matter

pH

5 (20 °C, 100 g/L in H2O)

mp

220 °C

bulk density

480 kg/m3

anion traces

chloride (Cl-): ≤0.005%

cation traces

Fe: ≤0.002%

storage temp.

2-30°C

SMILES string

[Co].[Na+].[Na+].[Na+].N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-]

InChI

1S/Co.6HNO2.3Na/c;6*2-1-3;;;/h;6*(H,2,3);;;/q;;;;;;;3*+1/p-6

InChI key

MUTOTFDDGIZNIK-UHFFFAOYSA-H

Application


  • One-pot synthesis of graphene-cobalt hydroxide composite nanosheets (Co/G NSs) for electrocatalytic water oxidation.: This article presents a study on the use of sodium hexanitrocobaltate(III) in a one-pot synthesis method for producing graphene-cobalt hydroxide composite nanosheets. These composites show significant potential for applications in electrocatalytic water oxidation, highlighting their importance in energy conversion and storage technologies (Mehmood R et al., 2018).

  • Nitrosation with Sodium Hexanitrocobaltate(III).: This research discusses the use of sodium hexanitrocobaltate(III) as a reagent for the nitrosation process. It provides valuable insights into the application of this compound in organic synthesis, demonstrating its effectiveness in introducing nitroso groups into organic molecules, which is critical for the development of pharmaceuticals and agrochemicals (Stefane B et al., 1997).

Analysis Note

Identity: passes test
Insoluble matter: ≤ 0.02 %
Chloride (Cl): ≤ 0.005 %
Fe (Iron): ≤ 0.002 %
Suitability for Potassium determination: passes test

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany


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Danger

Storage Class

5.1B - Oxidizing hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

Hazard Classifications

Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Ox. Sol. 2 - Resp. Sens. 1 - Skin Sens. 1



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