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Merck

8.22287

Hydrogen peroxide solution

30%, (stabilized) for synthesis

Synonym(s):

Hydrogen peroxide solution, Perhydrol

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About This Item

Linear Formula:
H2O2
CAS Number:
Molecular Weight:
34.01
NACRES:
NA.22
UNSPSC Code:
12352304
MDL number:
Beilstein/REAXYS Number:
3587191
Form:
liquid
Grade:
synthesis grade
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Product Name

Hydrogen peroxide 30%, (stabilized) for synthesis

grade

synthesis grade

Quality Segment

vapor pressure

18 hPa ( 20 °C), 23.3 mmHg ( 30 °C)

form

liquid

reaction suitability

reagent type: oxidant

pH

2-4 (20 °C in H2O)

bp

107 °C/1013 hPa

mp

-26 °C

density

1.11 g/cm3 at 20 °C

storage temp.

2-25°C

SMILES string

OO

InChI

1S/H2O2/c1-2/h1-2H

InChI key

MHAJPDPJQMAIIY-UHFFFAOYSA-N

Application

Hydrogen peroxide 30% can be used as an oxidizing agent:
  • To synthesize 5-bromo-2-nitropyridine from 5-bromo-2-aminopyridine in the presence of H2SO4.
  • For the oxidation of aromatic and aliphatic sulfides to sulfoxides or sulfones.
  • For the epoxidation of terminal olefins using a mixture of Na2WO4 dihydrate, (aminomethyl)phosphonic acid, and methyltrin-octylammonium hydrogensulfate.
  • To prepare adipic acid via oxidation of cyclohexanone and cyclohexanol in the presence of H2WO4 as a catalyst.
  • To convert cyclopentanone to δ-valerolactone via Baeyer−Villiger-oxidation in the presence of a solid acid catalyst.

Analysis Note

Assay (manganometric): 29.0 - 31.0 %
Density (d 20/4): 1.11 - 1.12 g/cm³

Disclaimer

The product is not intended for use as a biocide under global biocide regulations, including but not limited to the US EPA′s Federal Insecticide Fungicide and Rodenticide Act, the European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR), and others.


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 1

flash_point_f

not combustible

flash_point_c

not combustible



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