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Merck

427136

Cobalt(II) bromide

AnhydroBeads, −10 mesh, 99.99% trace metals basis

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About This Item

Linear Formula:
CoBr2
CAS Number:
Molecular Weight:
218.74
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-166-7
MDL number:
Assay:
99.99% trace metals basis
Grade:
synthesis grade
Form:
beads
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Product Name

Cobalt(II) bromide, AnhydroBeads, −10 mesh, 99.99% trace metals basis

InChI key

BZRRQSJJPUGBAA-UHFFFAOYSA-L

InChI

1S/2BrH.Co/h2*1H;/q;;+2/p-2

SMILES string

Br[Co]Br

grade

synthesis grade

product line

AnhydroBeads

assay

99.99% trace metals basis

form

beads

reaction suitability

core: cobalt

impurities

≤150.0 ppm Trace Metal Analysis

particle size

−10 mesh

density

4.909 g/mL at 25 °C (lit.)

application(s)

battery precursors
catalysts
material synthesis precursor

Quality Level

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Application

Used in the preparation of a new complex, Co(OESPz), which offers the possibility of intermolecular ferromagnetic interactions.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Muta. 2 - Resp. Sens. 1 - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Ricciardi, G. et al.
Inorganic Chemistry, 38, 1422-1422 (1999)
Yuefan Wang et al.
Chemical communications (Cambridge, England), 48(66), 8183-8185 (2012-03-24)
A cobalt-TMTU complex, derived from the in situ reduction of CoBr(2) with Zn in the presence of TMTU, can catalyze Pauson-Khand reaction at a balloon pressure of CO, which enables the synthesis of structurally diverse cyclopentenones. This catalytic system works
Ru-Pan Wang et al.
The journal of physical chemistry. C, Nanomaterials and interfaces, 121(45), 24919-24928 (2017-11-25)
We show that with 2p3d resonant inelastic X-ray scattering (RIXS) we can accurately determine the charge-transfer parameters of CoF
A C Blackburn et al.
Acta crystallographica. Section C, Crystal structure communications, 47 ( Pt 2), 282-286 (1991-02-15)
Tetraaquacobalt(II) bromide dihydrate, [Co(H2O)4]Br2 x 2H2O, Mr = 326.83, monoclinic, C2/m, a = 11.0158(12), b = 7.1694(10), c = 6.9111(10) A, beta = 124.761(7)degrees, V = 448.4(1) A3, Z = 2, F(000) = 314, Dx = 2.420 g cm-3, lambda(Mo

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