195596
sec-Butyllithium solution
1.4 M in cyclohexane
동의어(들):
Lithium-2-butanide, s-BuLi
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
CH3CH2CH(CH3)Li
CAS 번호:
Molecular Weight:
64.06
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587206
Concentration:
1.4 M in cyclohexane
Form:
liquid
form
liquid
Quality Segment
concentration
1.4 M in cyclohexane
density
0.769 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li]C(C)CC
InChI
1S/C4H9.Li/c1-3-4-2;/h3H,4H2,1-2H3;
InChI key
VATDYQWILMGLEW-UHFFFAOYSA-N
Application
sec-Butyllithium solution (1.4M in cyclohexane) has been used in the multi-step synthesis of 5-methyl-5,6-dihydrothymidine (5-MDHT) from thymidine. It has also been used in the copper-catalyzed asymmetric allylic alkylation (AAA) of allyl bromides, chlorides, and ethers in the presence of a chiral ligand.
Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
target_organs
Central nervous system
저장 등급
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 2
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react. 1