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346276

Tetrakis(acetonitrile)copper(I) hexafluorophosphate

Name: Tetrakis(acetonitrile)copper(I) hexafluorophosphate
Brand: ALDRICH

97%, solid

Synonym(s):

Copper(I) tetrakis(acetonitrile) hexafluorophosphate, Cuprous tetrakis(acetonitrile) hexafluorophosphate

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About This Item

Linear Formula:

[(CH₃CN)₄Cu]PF₆

CAS Number:

64443-05-6

Molecular Weight:

372.72

UNSPSC Code:

12161600

PubChem Substance ID:

24861387

NACRES:

NA.22

MDL number:

MFCD00064810

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Properties

Product Name

Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 97%

Quality Level

100

assay

97%

form

solid

reaction suitability

reagent type: catalyst, reagent type: catalyst
core: copper
reaction type: click chemistry

mp

160 °C (dec.) (lit.)

SMILES string

[Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F

InChI

1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1

InChI key

GNQXUMGHBSAQBV-UHFFFAOYSA-N

Description

Application

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.

It can also be used as a copper precursor:

For the formation of Cu₂S/CdS nanorod junctions by cationic exchange process.
To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF₆]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
For the synthesis of [Cu(NHC)₂]PF₆ complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.
In the synthesis of stimuli-responsive particle-based amphiphiles prepared by anisotropic click chemistry.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

346276-5G:4.548173138466E12 + 346276-25G:4.548173138459E12

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Articles

What is Click Chemistry? An Introduction

Explore click chemistry: efficient, high-yield reactions for drug discovery, bioconjugation, and green chemistry with simple conditions and wide applications.

Structural Characterization and Photochemical Properties of Mono-and Bimetallic Cu-Mabiq Complexes.

Stark HS, et al.

Inorganic Chemistry, 28(9), 095705-095705 (2018)

Synthesis and characterization of [Cu (NHC)2] X complexes: Catalytic and mechanistic studies of hydrosilylation reactions.

Diez-Gonzalez S, et al.

Chemistry?A European Journal , 14(1), 158-168 (2008)

Two luminescent pseudo-polymorphic cuprous complexes with different optical properties: Synthesis, characterization and TD-DFT calculations.

Tao XD, et al.

Polyhedron, 144(9), 36-43 (2018)

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