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Merck

649805

PEDOT, block PEG

solution, 1 wt. % dispersion in nitromethane, contains perchlorate as dopant

Synonym(s):

Aedotron C-NM, PEDOT-block-PEG, PEDOT-b-PEG

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About This Item

UNSPSC Code:
12352103
NACRES:
NA.23
MDL number:
Technical Service
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Product Name

Poly(3,4-ethylenedioxythiophene)-block-poly(ethylene glycol) solution, 1 wt % dispersion in nitromethane, contains perchlorate as dopant

contains

perchlorate as dopant

Quality Level

concentration

1 wt % dispersion in nitromethane

resistance

10,000-100,000 Ω/sq (spin cast thin films: typically 1-3 layers spun at 1,000 rpm)

work function

4.33 eV

description

40 nm (RMS roughness spin cast thin films)

particle size

600-1000 nm (in suspension)

conductivity

0.1-5.0 S/cm (bulk)

density

1.127 g/mL at 25 °C

General description

Aedotron polymers are solvent-dispersable forms of PEDOT. These are copolymers of doped PEDOT and a flexible, soluble polymer such as poly(ethylene glycol) (PEG). These colloidal dispersions are stabilized by the highly solvated PEG chains which sterically limit the aggregation of the PEDOT blocks. Aedotron polymers are neither acidic nor corrosive, it easily disperses in polar aprotic solvents. Perchlorate-doped copolymers typically have a higher conductivity with thin films that are more transparent.
Please follow this link for Aedotron/Oligotron selection guide table.

Application

Conducting polymer. Useful as anti-static layers, hole-transport layers in OLED′s and various organic electronics applications (flexible circuits, capacitors, batteries).
Nitromethane dispersions can be used to cast thin films on glass, ITO, silicon wafers and many polymeric substrates. Compatibility of the polymeric substrate with nitromethane should be tested in each case. Coat the substrate with a "pool" of the nitromethane dispersion. Thin transparent films are typically spun at 1000 RPM or higher speeds, but more conducting films can be obtained at lower speeds. A single layer spun at 1000 RPM is typically 75 nm thick.

Legal Information

Aedotron is a trademark of TDA Research, Inc.

Disclaimer

Store this product at room temperature (do not refrigerate or freeze). Some settling will normally occur. Agitate, sonicate, and filter prior to use. A plug of glass wool in a pipette can be used for easy filtration. The shelf life of this product will vary depending on how it is stored and handled. Product should be discarded if heavy aggregation occurs, or if sonication / filtering are inadequate to produce a good casting solution.


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Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 3 - Repr. 2

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

96.8 °F - closed cup

flash_point_c

36 °C - closed cup


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class I Designated Chemical Substances

prtr

Group 5: Self-reactive substances + Nitro compounds + Hazardous rank II + 2nd self-reactive materials

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

649805-25G:4548173926513 + 649805-VAR: + 649805-BULK:

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Articles

The application of conducting polymers at the interface with biology is an exciting new trend in organic electronics research.

各種PEDOT/PSS水分散溶液・ペレット、有機溶媒分散PEDOTについてご紹介いたします。有機溶媒分散PEDOTは、非酸性の有機分散液として使用可能であり、PEDOT/PSSに匹敵する導電性と光透過性をもつ膜を作製可能です。

In the field of organic printable electronics, such as OLEDs and organic photovoltaics (OPVs), improved organic conducting and semiconducting materials are needed. The progress in two fields is reviewed in this article.