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703540

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution

1.0 M in THF

Synonym(s):

TMPMgCl·LiCl

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About This Item

Empirical Formula (Hill Notation):
C9H18Cl2LiMgN
CAS Number:
898838-07-8
Molecular Weight:
242.40
NACRES:
NA.22
PubChem Substance ID:
329762048
UNSPSC Code:
12352103
MDL number:
MFCD12546030
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form

liquid

Quality Segment

100

reaction suitability

reaction type: Grignard Reaction

packaging

Sure/Seal™ of

concentration

1.0 M in THF, 20 % (w/w)

density

0.96 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl

InChI

1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2

InChI key

JHBZAAACZVPPRQ-UHFFFAOYSA-L

Application

Selective Deprotonations using Knochel-Hauser-Base
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Product of Albemarle US Inc
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

supp_hazards

EUH014,EUH019

Storage Class

3 - Flammable liquids

flash_point_f

5.0 °F

flash_point_c

-15 °C

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class I Designated Chemical Substances

prtr

Group 4: Flammable liquids + Type 1 petroleums + Hazardous rank II + Water insoluble liquid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

703540-500ML:4.5481733412E12 + 703540-100ML:4.548173295589E12

jan

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