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Merck

703559

Lanthanum(III) chloride bis(lithium chloride) complex solution

0.6 M in THF

Synonym(s):

Lanthanum trichloride lithium chloride complex

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About This Item

Linear Formula:
LaCl3 · 2LiCl
CAS Number:
Molecular Weight:
330.05
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.22
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form

liquid

Quality Segment

reaction suitability

reagent type: catalyst
core: lanthanum
reaction type: Grignard Reaction

packaging

Sure/Seal™ of

concentration

0.6 M in THF, 16 % (w/w)

density

1.05 g/mL at 25 °C

SMILES string

[Li]Cl.[Li]Cl.Cl[La](Cl)Cl

InChI

1S/5ClH.La.2Li/h5*1H;;;/q;;;;;+3;2*+1/p-5

InChI key

YSKOYVQYUJUXCN-UHFFFAOYSA-I

Application

Selective 1,2-Additions with LaCl3•2LiCl

  • Mediates Grignard additions
  • Reagent for metal exchange reactions
  • Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines

Legal Information

Product of Albemarle US Inc
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC


Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Sens. 1 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

Flash Point (°F)

62.6 °F

Flash Point (°C)

17 °C

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class I Designated Chemical Substances

prtr

Group 4: Flammable liquids + Type 1 petroleums + Hazardous rank II + Water insoluble liquid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

703559-BULK: + 703559-4X25ML: + 703559-25ML:4548173915142 + 703559-100ML:4548173295893 + 703559-VAR:

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