710733
2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide
Synonym(s):
1,1-Dimethylethyl-2-methyl-1-phenylpropyl nitroxide, tert-Butyl 1-phenyl-2-methylpropyl nitroxide, NMP universal alkoxyamine nitroxide
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About This Item
refractive index
n20/D 1.515
density
0.953 g/mL at 25 °C
storage temp.
−20°C
SMILES string
CC(C)C(N([O])C(C)(C)C)c1ccccc1
InChI
1S/C14H22NO/c1-11(2)13(15(16)14(3,4)5)12-9-7-6-8-10-12/h6-11,13H,1-5H3
InChI key
VGHCMXLEZFMZOZ-UHFFFAOYSA-N
General description
Application
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Ox. Liq. 3
Storage Class
5.1B - Oxidizing hazardous materials
wgk
WGK 3
flash_point_f
205.0 °F - closed cup
flash_point_c
96.1 °C - closed cup
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
Group 4: Flammable liquids + Type 3 petroleums + Hazardous rank III + Water insoluble liquid
fsl
710733-VAR: + 710733-250MG: + 710733-1G: + 710733-BULK:
jan
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Protocols
ウォーリック大学のProf. Dave Haddletonの研究グループによって実証された、ATRPによる重合。
RAFT（可逆的付加-開裂連鎖移動）重合によるPMMAおよびPVAcの典型的な重合手順をご紹介します。
We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.
Articles
Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator
ニトロキシドを介したラジカル重合（NMP）の概略とNMP開始剤について、実際のプロトコルを中心にご紹介します。
Micro Review：RAFT（可逆的付加／開裂連鎖移動）重合