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Merck

722987

2-Cyano-2-propyl benzodithioate

>97% (HPLC)

Synonym(s):

2-Cyanopropan-2-yl benzodithioate

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About This Item

Empirical Formula (Hill Notation):
C11H11NS2
CAS Number:
Molecular Weight:
221.34
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Quality Level

assay

>97% (HPLC)

form

solid or liquid

refractive index

n20/D 1.621

mp

28-31 °C

density

1.146 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(SC(=S)c1ccccc1)C#N

InChI

1S/C11H11NS2/c1-11(2,8-12)14-10(13)9-6-4-3-5-7-9/h3-7H,1-2H3

InChI key

IDSLBLWCPSAZBL-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylate and methacrylamide monomers. Chain Transfer Agent (CTA)

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Skin Sens. 1

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

>230.0 °F - closed cup

flash_point_c

> 110 °C - closed cup


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

722987-5G:4548173299563 + 722987-VAR: + 722987-BULK: + 722987-1G:4548173299556

jan


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Xiaohan Zhang et al.
Langmuir : the ACS journal of surfaces and colloids, 34(27), 7998-8006 (2018-06-28)
Amphiphilic poly( N-(2-hydroxypropyl)methacrylamide) copolymers ( pHPMA) bearing cholesterol side groups in phosphate buffer saline self-assemble into nanoparticles (NPs) which can be used as tumor-targeted drug carriers. It was previously shown by us that human serum albumin (HSA) interacts weakly with
Ryuichi Nakatani et al.
ACS applied materials & interfaces, 9(37), 31266-31278 (2017-03-18)
In this study, a series of perpendicular lamellae-forming poly(polyhedral oligomeric silsesquioxane methacrylate-block-2,2,2-trifluoroethyl methacrylate)s (PMAPOSS-b-PTFEMAs) was developed based on the bottom-up concept of creating a simple yet effective material by tailoring the chemical properties and molecular composition of the material. The
Thomas Swift et al.
Soft matter, 12(9), 2542-2549 (2016-01-30)
Fluorescence spectroscopy on a series of aqueous solutions of poly(acrylic acid) containing a luminescent label showed that polymers with molar mass, Mn < 16.5 kDa did not exhibit a pH responsive conformational change, which is typical of higher molar mass
Sungyoup Hong et al.
PloS one, 12(1), e0169262-e0169262 (2017-01-07)
In this report, we demonstrate the pH-dependent, in vitro antimicrobial activity of a cationic, amphiphilic random copolymer against clinical isolates of drug-resistant Staphylococcus aureus. The polymer was developed toward a long-term goal of potential utility in the treatment of skin
Laura Marcela Forero Ramirez et al.
Carbohydrate polymers, 224, 115153-115153 (2019-09-02)
A multi-reactive polysaccharide-based transurf (acting both as macro-Chain Transfer Agent and stabilizer) was used to confine RAFT polymerization of methyl methacrylate (MMA) at the oil/water (o/w) miniemulsion interface. Dithiobenzoate groups and hydrophobic aliphatic side chains were introduced onto dextran, conferring

Articles

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

See All

Protocols

ウォーリック大学のProf. Dave Haddletonの研究グループによって実証された、ATRPによる重合。

RAFT(可逆的付加-開裂連鎖移動)重合によるPMMAおよびPVAcの典型的な重合手順をご紹介します。

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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