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Merck

736236

2-Cyanopropan-2-yl N-methyl-N-(pyridin-4-yl)carbamodithioate

97% (HPLC)

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About This Item

Empirical Formula (Hill Notation):
C11H13N3S2
CAS Number:
Molecular Weight:
251.37
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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InChI

1S/C11H13N3S2/c1-11(2,8-12)16-10(15)14(3)9-4-6-13-7-5-9/h4-7H,1-3H3

SMILES string

CN(C(=S)SC(C)(C)C#N)c1ccncc1

InChI key

PYVIBYAVTHICFS-UHFFFAOYSA-N

assay

97% (HPLC)

form

solid

mp

97-102 °C

storage temp.

2-8°C

Quality Level

Application

Switchable RAFT agent for controlled radical polymerization. The neutral form is well-suited for polymerization of vinyl esters and vinyl amides (LAMs), and the protonated form is well-suited for styrenes acrylates and methacrylates (MAMs). Chain Transfer Agent (CTA)

pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

Resp. Sens. 1 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

736236-5G:4548173306308 + 736236-BULK: + 736236-1G:4548173306292 + 736236-VAR:

jan


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

Universal (Switchable) RAFT agents allow for the polymerization of both less activated and more activated monomers and are ideal for the synthesis of well-defined block copolymers.

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Protocols

ウォーリック大学のProf. Dave Haddletonの研究グループによって実証された、ATRPによる重合。

RAFT(可逆的付加-開裂連鎖移動)重合によるPMMAおよびPVAcの典型的な重合手順をご紹介します。

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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