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809330

Fe/ppm Pd for nitro group reductions

solid

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About This Item

UNSPSC Code:
12161600
NACRES:
NA.22
MDL number:
MFCD00011005
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Product Name

Fe/ppm Pd for nitro group reductions,

form

solid

Quality Segment

100

composition

FeCl2 (372870), 23.3-27.4 wt. % , MgCl2 (M8266), 15.3-18.8 wt. % , Pd (203939), <0.3 wt. % , THF (186562), 53.5-61.6 wt. %

reaction suitability

core: iron, reagent type: catalyst

storage temp.

2-8°C

SMILES string

[Fe](Cl)(Cl)Cl

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

Application

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

Other Notes

Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature
Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead

Disclaimer

Handle under nitrogen and store under argon in refrigerator.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH018,EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

1.4 °F

flash_point_c

-17 °C

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Group 4: Flammable liquids + Type 1 petroleums + Hazardous rank II + Water insoluble liquid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

809330-500MG: + 809330-BULK: + 809330-VAR:

jan

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