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Merck

227676

Nickel(II) sulfate hexahydrate

ACS reagent, ≥98%

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About This Item

Linear Formula:
NiSO4 · 6H2O
CAS Number:
Molecular Weight:
262.85
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-104-9
MDL number:
Assay:
≥98%
Grade:
ACS reagent
Form:
crystals
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grade

ACS reagent

Quality Segment

vapor density

2.07 (vs air)

assay

≥98%

form

crystals

reaction suitability

reagent type: catalyst
core: nickel

impurities

≤0.002% N compounds, ≤0.005% insolubles

anion traces

chloride (Cl-): ≤0.001%

cation traces

Ca: ≤0.005%, Co: ≤0.002%, Cu: ≤0.005%, Fe: ≤0.001%, K: ≤0.01%, Mg: ≤0.005%, Mn: ≤0.002%, Na: ≤0.05%

SMILES string

O.O.O.O.O.O.[Ni++].[O-]S([O-])(=O)=O

InChI

1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2

InChI key

RRIWRJBSCGCBID-UHFFFAOYSA-L

General description

Nickel(II) sulfate hexahydrate is a hydrated nickel salt. It is used as a nickel precursor for the preparation of Ni-based catalysts.

Application

Nickel(II) sulfate hexahydrate (NiSO4 6H2O) can be used as a nickel precursor for the preparation of:     
  • Palladium-nickel bimetallic nanoparticles (Pd-Ni) which are used as a catalyst in the Buchwald-Hartwig amination reaction.
  • NiFe2O4 nanoparticles (NPs) applicable for the fabrication of a glucose biosensor.

It can also be used as a recyclable catalyst in:      
  • The synthesis of α-aminophosphonates via a one-pot three-component reaction of aromatic aldehydes, primary amines, and diethylphosphite.      
  • Trifluoromethylation of arylamine in the presence of Langlois′ reagent (CF3SO2Na) as CF3 source and potassium persulfate (K2S2O8) as initiator.



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signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

target_organs

Respiratory Tract

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Specified Class I Designated Chemical Substances

prtr

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

227676-100G:4.548173293769E12 + 227676-500G:4.548173293783E12 + 227676-5G:4.54817329379E12 + 227676-2.5KG:4.548173293776E12

jan



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