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Merck

F3629

Ammonium iron(III) sulfate dodecahydrate

greener alternative

≥99%, ReagentPlus®

Synonym(s):

Ammonium iron disulfate dodecahydrate, Ammonium ferric sulfate dodecahydrate

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About This Item

Linear Formula:
NH4Fe(SO4)2 · 12H2O
CAS Number:
Molecular Weight:
482.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
233-382-4
MDL number:
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Product Name

Ammonium iron(III) sulfate dodecahydrate, ReagentPlus®, ≥99%

Quality Level

product line

ReagentPlus®

assay

≥99%

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

39-41 °C (lit.)

greener alternative category

storage temp.

2-8°C

SMILES string

N.O.O.O.O.O.O.O.O.O.O.O.O.[Fe+3].OS([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Fe.H3N.2H2O4S.12H2O/c;;2*1-5(2,3)4;;;;;;;;;;;;/h;1H3;2*(H2,1,2,3,4);12*1H2/q+3;;;;;;;;;;;;;;;/p-3

InChI key

LCPUDZUWZDSKMX-UHFFFAOYSA-K

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Ammonium iron(III) sulfate dodecahydrate can be used as:
  • A catalyst to synthesize 1,4-dihydropyridines via one-pot three-component condensation reaction of dimedone, aldehydes, and 3-aminocrotonate in ethanol.
  • An additive in the reduction of aromatic nitro compounds to the corresponding amino compounds in the presence of alumina-supported hydrazine hydrate as a catalyst.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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R Săndulescu et al.
Journal of pharmaceutical and biomedical analysis, 14(8-10), 951-958 (1996-06-01)
The method is based upon the reaction between fluoride ions and the coloured complex of Fe(III) with methyl salicylate to form the stable, colourless hexaflouride complex of iron. The conditions of the method (pH, time and combination ratio) were studied
Andrew J Ghio et al.
American journal of physiology. Lung cellular and molecular physiology, 283(3), L563-L572 (2002-08-10)
The iron chelator deferoxamine has been reported to inhibit both xanthine oxidase (XO) and xanthine dehydrogenase activity, but the relationship of this effect to the availability of iron in the cellular and tissue environment remains unexplored. XO and total xanthine
J G Reinhold et al.
The Journal of nutrition, 116(6), 1007-1017 (1986-06-01)
The effects of pH, ascorbate, citrate and dietary fiber on retention of ferrous and ferric iron by jejuno-ileal segments of rat intestine were examined in vivo. Iron was introduced in an isosmotic solution of sodium chloride and dextrose buffered by