Key Documents

687596

(11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide

Name: (11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium bromide
Brand: ALDRICH

Nagase purity

Select a Size

Change View

About This Item

Empirical Formula (Hill Notation):

C₄₂H₃₆BrF₆N

CAS Number:

887938-70-7

Molecular Weight:

748.64

NACRES:

NA.22

PubChem Substance ID:

329761140

UNSPSC Code:

12352005

MDL number:

MFCD09264271

Technical Service

Need help? Our team of experienced scientists is here for you.

Let Us Assist

Properties

Quality Segment

100

form

solid

mp

223-228 °C

functional group

fluoro

SMILES string

CCCC[N+]1(CCCC)Cc2c(cc3ccccc3c2-c4c(C1)c(cc5ccccc45)-c6cc(F)c(F)c(F)c6)-c7cc(F)c(F)c(F)c7

InChI

1S/C42H36F6N.BrH/c1-3-5-15-49(16-6-4-2)23-33-31(27-19-35(43)41(47)36(44)20-27)17-25-11-7-9-13-29(25)39(33)40-30-14-10-8-12-26(30)18-32(34(40)24-49)28-21-37(45)42(48)38(46)22-28;/h7-14,17-22H,3-6,15-16,23-24H2,1-2H3;1H/q+1;/p-1

InChI key

LOMUZNOWQYZTRP-UHFFFAOYSA-M

Description

Application

Potent phase transfer organocatalyst for asymmetric α-alkylation of glycine derivatives at extremely low loadings.

Features and Benefits

Maruoka phase-transfer catalysts are:

Operationally straightforward
Environmentally friendly
Relatively mild reaction conditions
Reactions conducted in aqueous media
Low catalyst loading

Legal Information

Product of Nagase & Co. Ltd.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c