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904694

Ir(p-CF3-ppy)3

≥95%, powder or crystals

Synonym(s):

Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium

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About This Item

Empirical Formula (Hill Notation):
C36H21F9IrN3
CAS Number:
500295-52-3
Molecular Weight:
858.77
MDL number:
MFCD31657272
UNSPSC Code:
12161600
NACRES:
NA.22
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Product Name

Ir(p-CF3-ppy)3, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

465 nm

SMILES string

[Ir]741([NH]8=C(c9c7cc(cc9)C(F)(F)F)C=CC=C8)([NH]5=C(c6c4cc(cc6)C(F)(F)F)C=CC=C5)[NH]2=C(c3c1cc(cc3)C(F)(F)F)C=CC=C2

InChI

1S/3C12H7F3N.Ir/c3*13-12(14,15)10-6-4-9(5-7-10)11-3-1-2-8-16-11;/h3*1-4,6-8H;

InChI key

ZLVNAIXHGHEODI-UHFFFAOYSA-N

Application

This photocatalyst facilitates a variety of transformations using visible light, including the defluorination of arenes.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis

Photocatalytic C–F alkylation; facile access to multifluorinated arenes

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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