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366374

Zinc chloride solution

0.5 M in THF

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About This Item

Linear Formula:
ZnCl2
CAS Number:
7646-85-7
Molecular Weight:
136.30
NACRES:
NA.55
PubChem Substance ID:
329755428
UNSPSC Code:
12352302
MDL number:
MFCD00011295
Form:
liquid
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form

liquid

Quality Segment

100

concentration

0.5 M in THF, 470-600 mmol/L (silver nitrate titration)

density

0.948 g/mL at 25 °C

SMILES string

Cl[Zn]Cl

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

General description

Zinc chloride solution is a colorless liquid that contains zinc chloride dissolved in THF. Its synthesis has been reported.

Application

Zinc chloride solution was used in the synthesis of the ferrocenylarenes.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

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Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

109-99-9

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