128910
N,O-Bis(trimethylsilyl)acetamide
synthesis grade, ≥95%
동의어(들):
BSA
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
CH3C[=NSi(CH3)3]OSi(CH3)3
CAS 번호:
Molecular Weight:
203.43
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
233-892-7
Beilstein/REAXYS Number:
1306669
MDL number:
Assay:
≥95%
Form:
liquid
grade
synthesis grade
assay
≥95%
form
liquid
refractive index
n20/D 1.417 (lit.)
bp
71-73 °C/35 mmHg (lit.)
density
0.832 g/mL at 20 °C (lit.)
functional group
amine
SMILES string
C\C(O[Si](C)(C)C)=N/[Si](C)(C)C
InChI
1S/C8H21NOSi2/c1-8(9-11(2,3)4)10-12(5,6)7/h1-7H3/b9-8+
InChI key
SIOVKLKJSOKLIF-CMDGGOBGSA-N
General description
N,O-Bis(trimethylsilyl)acetamide(BSA) is a powerful silylating agent for the protection of amides, amines, alcohols, carboxylic acids, enols and phenols. It can also be used as a Bronsted base precursor in Tsuji–Trost reactions. Additionally, it can be used to activate different functional groups during the production of nucleosides, peptides, and heterocycles.
Application
Reagent for the regioselective desulfation of polysaccharide sulfates. Also used to prepare trimethylsilyl ethers of carbohydrates and alcohols.
Derivatization reagent for GC-MS analysis of phenolic acids in fruits.
Features and Benefits
BSA is good moisture absorbent.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
supp_hazards
저장 등급
3 - Flammable liquids
wgk
WGK 3
flash_point_f
111.2 °F - closed cup
flash_point_c
44 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
N, O-Bis (trimethylsilyl) acetamide
Claraz A
Synlett, 24(5), 657-658 (2013)
Mohammad Saraji et al.
Journal of separation science, 29(9), 1223-1229 (2006-07-13)
A simple analytical procedure based on single-drop microextraction combined with in-syringe derivatization and GC-MS was developed for determination of some phenolic acids in fruits and fruit juices. Cinnamic acid, o-coumaric acid, caffeic acid, and p-hydroxybenzoic acid were used as model
Carbohydrate Research, 237, 313-313 (1992)