214000
TEMPO
98%
๋ ์นํ๊ฒฝ์ ์ธ ๋์
๋์์ด(๋ค):
2,2,6,6-Tetramethylpiperidine 1-oxyl, 2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical, TEMPO
์กฐ์ง ๋ฐ ๊ณ์ฝ ๊ฐ๊ฒฉ์ ๋ณด๋ ค๋ฉด ๋ก๊ทธ์ธ๋ฅผ ํด๋ฆญํฉ๋๋ค.
ํฌ๊ธฐ ์ ํ
๋ณด๊ธฐ ๋ณ๊ฒฝ
์ ํ์ ๋ณด (DICE ๋ฐฐ์ก ์ ๋น์ฉ ๋ณ๋)
์คํ์(Hill ํ๊ธฐ๋ฒ):
C9H18NO
CAS ๋ฒํธ:
Molecular Weight:
156.25
UNSPSC Code:
12352119
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-888-8
Beilstein/REAXYS Number:
1422418
MDL number:
Assay:
98%
Form:
solid
๊ธฐ์ ์๋น์ค
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๋์ ๋ฌธ์Quality Segment
assay
98%
form
solid
reaction suitability
reagent type: oxidant
sustainability
Sustainability features
mp
36-38 ยฐC (lit.)
storage temp.
2-8ยฐC
SMILES string
CC1(C)CCCC(C)(C)N1[O]
InChI
1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3
InChI key
QYTDEUPAUMOIOP-UHFFFAOYSA-N
General description
TEMPO (2,2,6,6-Tetramethylpiperidin-1-oxyl) is a stable free radical commonly used as an oxidizing agent in organic synthesis. Copper/TEMPO has been utilized in the catalytic oxidation of primary alcohols to aldehydes.
This product aligns with one or more of the 12 Principles of Green Chemistry Find details here.
Application
TEMPO can be used:
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
- As a catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions.
- As a catalytic oxidant in the iodobenzene diacetae oxidation of nerol to neral.
- For trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene.
- In the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
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๊ฒฝ๊ณ ์ด
Danger
์ํ ์ฝ๋
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C
์ ์ฅ ๋ฑ๊ธ
8A - Combustible corrosive hazardous materials
์ธํ์ (F)
152.6 ยฐF - closed cup
์ธํ์ (ยฐC)
67 ยฐC - closed cup
๊ฐ์ธ ๋ณดํธ ์ฅ๋น(PPE)
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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