225908
Allylmagnesium chloride solution
2.0 M in THF
동의어(들):
Allyl magnesium chloride, Allylchloromagnesium, Allylmagnesium chloride, Chloro-2-propen-1-ylmagnesium
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
CH2=CHCH2MgCl
CAS 번호:
Molecular Weight:
100.83
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587316
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Kilo-Lab® of , Sure/Seal™ of
concentration
2.0 M in THF
density
0.995 g/mL at 25 °C
SMILES string
Cl[Mg]CC=C
InChI
1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1
InChI key
PLYLAFITHJUEGX-UHFFFAOYSA-M
General description
Allylmagnesiumchloride solution is an organic compound commonly used as a Grignard reagent inchemical reactions. It is used for the allylation of carbonyl compounds, such as aldehydes and ketones.
Application
Allylmagnesium chloride solution is used as a Grignard reagent in the preparation of:
- Antipsychotic clopixol.
- Polysilane–crown ether polymer (PSEC) using hexachloroplatinic acid as a catalyst.
- 1,7-disubstituted-1,2,3,4-tetrahydroisoquinolinesfrom 3,4-dihydroisoquinoline.
Legal Information
Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
저장 등급
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
1.4 °F - closed cup - Solvent
flash_point_c
-17 °C - closed cup - Solvent
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1