346276
Tetrakis(acetonitrile)copper(I) hexafluorophosphate
97%, solid
동의어(들):
Copper(I) tetrakis(acetonitrile) hexafluorophosphate, Cuprous tetrakis(acetonitrile) hexafluorophosphate
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크기 선택
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제품정보 (DICE 배송 시 비용 별도)
Linear Formula:
[(CH3CN)4Cu]PF6
CAS 번호:
Molecular Weight:
372.72
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
제품 이름
Tetrakis(acetonitrile)copper(I) hexafluorophosphate, 97%
Quality Segment
assay
97%
form
solid
reaction suitability
reagent type: catalyst, reagent type: catalyst
core: copper
reaction type: click chemistry
mp
160 °C (dec.) (lit.)
SMILES string
[Cu+].CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F
InChI
1S/4C2H3N.Cu.F6P/c4*1-2-3;;1-7(2,3,4,5)6/h4*1H3;;/q;;;;+1;-1
InChI key
GNQXUMGHBSAQBV-UHFFFAOYSA-N
Application
Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:
It can also be used as a copper precursor:
- For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
- To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
- To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
- For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.
- In the synthesis of stimuli-responsive particle-based amphiphiles prepared by anisotropic click chemistry.
저장 등급
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
문서
Explore click chemistry: efficient, high-yield reactions for drug discovery, bioconjugation, and green chemistry with simple conditions and wide applications.
클릭 화학 탐구: 단순한 조건과 광범위한 응용을 통해 신약 개발, 생체접합 및 친환경 화학 분야를 위한 효율적이고 고수율 반응.
Two luminescent pseudo-polymorphic cuprous complexes with different optical properties: Synthesis, characterization and TD-DFT calculations.
Tao XD, et al.
Polyhedron, 144(9), 36-43 (2018)
Tetrakis (acetonitrile) copper (I) Hexafluorophosphate as an Efficient Catalyst for the Synthesis of Triazolo [1, 2-a] indazole-1, 3, 8-trione and 2Hindazolo [2, 1-b] phthalazine-trione Derivatives.
Azarifar D, et al.
Letters in Organic Chemistry, 9(2), 128-132 (2012)
Synthesis and characterization of [Cu (NHC)2] X complexes: Catalytic and mechanistic studies of hydrosilylation reactions.
Diez-Gonzalez S, et al.
Chemistry?A European Journal , 14(1), 158-168 (2008)