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673293

Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chloride

greener alternative

solid

동의어(들):

Cp*RuCl(PPh3)2, Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)

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제품정보 (DICE 배송 시 비용 별도)

Linear Formula:
[(C10H15)Ru(P((C6H5)3))2Cl]
CAS 번호:
92361-49-4
Molecular Weight:
796.32
UNSPSC Code:
12161600
PubChem Substance ID:
24885155
NACRES:
NA.22
MDL number:
MFCD09038426
기술 서비스
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제품 이름

Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chloride,

form

solid

Quality Segment

100

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: click chemistry

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

128 °C (D)

greener alternative category

Aligned

storage temp.

2-8°C

SMILES string

Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7

InChI

1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1

InChI key

KLXKSZDVKAWYRT-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is a versatile catalyst for regioselective 3+2 cycloaddition of azides and alkynes (RuAAC), producing 1,5-disubstituted triazoles. Click here for more information.

Application

Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".
Versatile catalyst for living radical polymerization

저장 등급

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

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시험 성적서(COA)

Lot/Batch Number
MKCZ7077
MKCX3602
MKCV8801
MKCR2038
MKCS6094

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문서 라이브러리 방문

문서

What is Click Chemistry? An Introduction

Explore click chemistry: efficient, high-yield reactions for drug discovery, bioconjugation, and green chemistry with simple conditions and wide applications.

클릭 화학이란 무엇인가? 입문

클릭 화학 탐구: 단순한 조건과 광범위한 응용을 통해 신약 개발, 생체접합 및 친환경 화학 분야를 위한 효율적이고 고수율 반응.

Li Zhang et al.
Journal of the American Chemical Society, 127(46), 15998-15999 (2005-11-17)
Cp*RuCl(PPh3)2 is an effective catalyst for the regioselective "fusion" of organic azides and terminal alkynes, producing 1,5-disubstituted 1,2,3-triazoles. Internal alkynes also participate in this catalysis, resulting in fully substituted 1,2,3-triazoles.
Metal-catalyzed living radical polymerization.
M Kamigaito et al.
Chemical reviews, 101(12), 3689-3746 (2001-12-13)