703540
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
1.0 M in THF
동의어(들):
TMPMgCl·LiCl
조직 및 계약 가격을 보려면 로그인를 클릭합니다.
크기 선택
보기 변경
제품정보 (DICE 배송 시 비용 별도)
실험식(Hill 표기법):
C9H18Cl2LiMgN
CAS 번호:
Molecular Weight:
242.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
form
liquid
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
1.0 M in THF, 20 % (w/w)
density
0.96 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl
InChI
1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
InChI key
JHBZAAACZVPPRQ-UHFFFAOYSA-L
Application
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.
Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Legal Information
Product of Albemarle US Inc
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
supp_hazards
저장 등급
3 - Flammable liquids
flash_point_f
5.0 °F
flash_point_c
-15 °C
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system