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Merck

243590

Potassium perrhenate

99%

Synonym(s):

Potassium oxido(trioxo)rhenium, Potassium tetraoxorhenate(1-)

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About This Item

Linear Formula:
KReO4
CAS Number:
Molecular Weight:
289.30
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-953-8
MDL number:
Assay:
99%
Form:
powder
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InChI key

QFKRWIFGDGKWLM-UHFFFAOYSA-N

InChI

1S/K.4O.Re/q+1;;;;-1;

SMILES string

[K+].[O-][Re](=O)(=O)=O

assay

99%

form

powder

reaction suitability

core: potassium

refractive index

n20/D 1.643 (lit.)

mp

550 °C (lit.)

density

4.887 g/mL at 25 °C (lit.)

Quality Level

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Application

The reduction of KReO4 in the preparation of cyclopentadienyltricarbonylrhenium complexes has potential as a model for the syntheses of technetium and rhenium organometallic radiopharmaceuticals.

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Spradau, T.W. Katzenellenbogen, J.A.
Organometallics, 17, 2009-2009 (1998)
Yuee Feng et al.
Inorganic chemistry, 48(23), 11058-11066 (2009-11-06)
The detailed syntheses of complexes of the form [Re(O)(X)(RNCH(2)CH(2))(2)N(Me)] (X = Me, Cl, I, R = mesityl, C(6)F(5)), 1-3, incorporating diamidoamine ancillary ligands are described. X-ray crystal structures for the complexes [Re(O)(Me)((C(6)F(5))NCH(2)CH(2))(2)N(Me)], 1a, [Re(O)(I)((C(6)F(5))N CH(2)CH(2))(2)N(Me)], 3a, and [Re(O)(I)((Mes)NCH(2))(2)N(Me)], 3b, are
Rui Cao et al.
Inorganic chemistry, 50(19), 9499-9507 (2011-08-30)
We describe a multidentate tripodal ligand in which three pendant arms carrying di(2-picolyl)amine units are linked to the ortho positions of a tris(o-xylyl) scaffold, providing N(CH(2)-o-C(6)H(4)CH(2)N(CH(2)py)(2))(3) (L). Reaction of L with CuCl(2) in the presence of hexafluorophosphate anion afforded blue
New sequencing technique produces high-resolution map of 5-hydroxymethylcytosine.
Jonathan Wilkinson
Epigenomics, 4(3), 249-249 (2012-08-10)
Julien Le Gal et al.
Journal of inorganic biochemistry, 105(6), 880-886 (2011-04-23)
Assembly of independent chemical modules through oxorhenium coordination by a NS(2)+S chelation motif was applied to the synthesis of RGD (Arg-Gly-Asp) analogs. Modules were assembled through oxorhenium chelation to give a series of 18 metal complexes in good yields and

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