359297
Sodium ethanethiolate
technical grade, 80%
Synonym(s):
Ethanethiol sodium salt, Ethyl mercaptan sodium salt
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About This Item
Linear Formula:
CH3CH2SNa
CAS Number:
Molecular Weight:
84.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3593647
Assay:
80%
Product Name
Sodium ethanethiolate, technical grade, 80%
InChI
1S/C2H6S.Na/c1-2-3;/h3H,2H2,1H3;/q;+1/p-1
SMILES string
CCS[Na]
InChI key
QJDUDPQVDAASMV-UHFFFAOYSA-M
grade
technical grade
assay
80%
Quality Level
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Application
Sodium ethanethiolate may be used in the equilibrium titrations in N-methylformamide of G-25 gel filtered (ox)-state FeMo cofactor [FeMoco(ox)] from Azotobacter vinelandii nitrogenase. It may be used in the synthesis of a series of hybrid compounds combining the pharmacophoric redox moieties of vitamin E and key features responsible for the antiarrhythmic properties of the class I antiarrhythmics procainamide and lidocaine.
General description
Reaction of FeCl2 or FeCl3 with sodium ethanethiolate in N-methylformamide (NMF) has been evaluated. Reaction of sodium ethanethiolate with substituted 1,2-dithiole-3-thiones has been studied.
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Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Reactivity of substituted 1, 2-dithiole-3-thiones with sodium ethanethiolate: a convenient route to a novel heterocycle.
Largeron M, et al.
Tetrahedron, 43(15), 3421-3428 (1987)
P Frank et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 6(7), 683-697 (2001-10-30)
Equilibrium titrations in N-methylformamide (NMF) of G-25 gel filtered (ox)-state FeMo cofactor [FeMoco(ox)] from Azotobacter vinelandii nitrogenase were carried out using sodium ethanethiolate and followed using UV/Vis absorption spectroscopy. For Fe-Moco(ox), a non-linear least squares (NLLSQ) fit to the data
Patrick Frank et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 10(4), 373-382 (2005-05-03)
The reaction of FeCl(2) or FeCl(3) with sodium ethanethiolate (SEt) in N-methylformamide (NMF) has been reevaluated to rectify a previous Fe(II) oxidation artifact. On titrating Fe(II) with EtS(-) concentrations up to 12 mol Eq, new features in the UV/vis spectrum
Maria Koufaki et al.
Bioorganic & medicinal chemistry, 11(23), 5209-5219 (2003-11-08)
We have synthesized a series of hybrid compounds combining the pharmacophoric redox moieties of vitamin E and key features responsible for the antiarrhythmic properties of the class I antiarrhythmics procainamide and lidocaine. Procainamide analogue (2a) and lidocaine analogues (14a) and
Pinar Kasaplar et al.
Bioorganic chemistry, 38(5), 186-189 (2010-07-27)
The mechanism of action for alpha,beta-unsaturated lactones can be explained by their Michael acceptor properties. They have the potential of being covalently binding inhibitors by accepting nucleophiles from target proteins. In this work, Michael addition reactions of ethanethiol with 6-bicycloaryl
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