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Merck

A8509

Lithium acetoacetate

≥90% (HPLC)

Synonym(s):

Acetoacetic acid lithium salt

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About This Item

Linear Formula:
CH3COCH2COOLi
CAS Number:
Molecular Weight:
108.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5774841
Assay:
≥90% (HPLC)
Form:
powder
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Quality Level

assay

≥90% (HPLC)

form

powder

storage temp.

−20°C

SMILES string

[Li+].CC(=O)CC([O-])=O

InChI

1S/C4H6O3.Li/c1-3(5)2-4(6)7;/h2H2,1H3,(H,6,7);/q;+1/p-1

InChI key

UTLRZTUJSMCBHB-UHFFFAOYSA-M

Application

Lithium acetoacetate can be used as an acetoacetate standard for the measurement of acetoacetate in biological samples. It can also be used for the preparation of sodium acetoacetate.


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Preparation of crystalline lithium acetoacetate.
Hall LM
Analytical Biochemistry, 3(1), 75-80 (1962)
Cristian Palmiere et al.
Legal medicine (Tokyo, Japan), 14(1), 17-20 (2011-12-20)
Isopropyl alcohol (IPA) is widely used as an industrial solvent and cleaning fluid. After ingestion or absorption, IPA is converted into acetone by alcohol dehydrogenase. However, in ketosis, acetone can be reduced to IPA. The aim of this study was
Hao Liang et al.
Journal of Cancer, 10(16), 3735-3745 (2019-07-25)
BDH2 is a short-chain dehydrogenase/reductase family member involved in several biological and pathological processes, including the utilization of cytosolic ketone bodies, immunocyte regulation and tumor progression. In this study, we first revealed that BDH2 was downregulated in HCC tissues by