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Merck

13468

Sodium sulfide hydrate

≥60%, scales

Synonym(s):

μ-Sulfidedisodium hydrate

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About This Item

Empirical Formula (Hill Notation):
Na2S · xH2O
CAS Number:
27610-45-3
Molecular Weight:
78.04 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
57647096
UNSPSC Code:
12161600
EC Number:
215-211-5
MDL number:
MFCD00003498

Key Documents

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InChI key

CXPWOVUZRAFMDA-UHFFFAOYSA-N

InChI

1S/2Na.S

SMILES string

[Na]S[Na]

form

scales

reaction suitability

core: sodium, reagent type: catalyst

concentration

≥60%

anion traces

chloride (Cl-): ≤100 mg/kg

storage temp.

2-8°C

Quality Level

100

Related Categories

General description

May contain up to 40% water.

Application

Nucleophile and reducing agent derived from H2S; reagent for the synthesis of thiols, thioethers, and acyclic sulfides, di-, and polysulfides; reduces aromatic nitro compounds to amines; reduces sulfoxides to sulfides.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

supp_hazards

EUH031

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB6356
SDBB4981
SDBB2637
STBL3845
SDBB1085

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Vanda Cerè et al.
The Journal of organic chemistry, 70(2), 664-669 (2005-01-18)
Optically pure enantiomers of the chiral tetrahydroxythiepane derivative 3,6-dihydroxy-4,5-O-isopropylidene-thiepane (3) are obtained using a novel protocol in which a library of all possible stereoisomers of 3 is synthesized, followed by two-step stereoselective chromatography, using, first, conventional achiral and, then, chiral
Total synthesis of xerulinic acid.
Achim Sorg et al.
Angewandte Chemie (International ed. in English), 43(34), 4523-4526 (2004-09-02)
Krzysztof Walczyński et al.
European journal of medicinal chemistry, 40(1), 15-23 (2005-01-12)
In search for a new lead of non-imidazole histamine H3-receptor antagonists, a series of 1[(2-thiazolopyridine)-4-n-propyl]piperazines, the analogous 1-[(2-oxazolopyridine)-4-npropyl]piperazines, 1-[(2-benzothiazole)-4-n-propyl]piperazine and 1-[(2-benzooxazole)4-n-propyl]piperazine were prepared and in vitro tested as H3-receptor antagonists (the electrically evoked contraction of the guinea-pig jejunum). It appeared
Feixiang Zan et al.
Water research, 182, 115960-115960 (2020-07-06)
Volatile fatty acids (VFAs), the intermediate of the anaerobic process, are considered to be the critical, high-sensitive and reliable indicators of the process stability. Close monitoring and control of VFAs are paramount for the efficient operation of the anaerobic reactors.
Reza Sahraei et al.
Nanotechnology, 28(47), 475604-475604 (2017-10-12)
We report here on a one-pot, mild and low cost aqueous-based synthetic route for the preparation of colloidally stable and highly luminescent dual-doped Ag,Ni:ZnCdS/ZnS core/shell quantum dots (QDs). The pure dopant emission of the Ni-doped core/shell QDs was found to
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