T24007
Tetramethylsilane
ACS reagent, NMR grade, ≥99.9%
Synonym(s):
TMS
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About This Item
Linear Formula:
Si(CH3)4
CAS Number:
Molecular Weight:
88.22
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-899-1
Beilstein/REAXYS Number:
1696908
MDL number:
Assay:
≥99.9%
Grade:
ACS reagent
Technique(s):
NMR: suitable
Bp:
26-28 °C (lit.)
Vapor pressure:
11.66 psi ( 20 °C)
InChI
1S/C4H12Si/c1-5(2,3)4/h1-4H3
SMILES string
C[Si](C)(C)C
InChI key
CZDYPVPMEAXLPK-UHFFFAOYSA-N
grade
ACS reagent
vapor pressure
11.66 psi ( 20 °C)
assay
≥99.9%
Quality Level
form
liquid
autoignition temp.
842 °F
expl. lim.
0.34-6.3 %
technique(s)
NMR: suitable
evapn. residue
≤0.05%
refractive index
n20/D 1.358 (lit.)
bp
26-28 °C (lit.)
mp
−99 °C (lit.)
density
0.648 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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Application
Tetramethylsilane can be used as:
- A precursor to synthesize α-SiC by chemical vapor deposition.
- A reactant to synthesize 1,3,5,7-tetramethyladamantane from adamantane in the presence of aluminum chloride and dichloromethane.
- A solvent for the hydroaminomethylation of 1-octene with morpholine.
- A methylating reagent for the conversion of germanium tetrachloride to tetramethylgermanium, trimethylgermanium chloride, dimethylgermanium dichloride or methylgermanium trichloride.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 1
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-16.6 °F - closed cup
flash_point_c
-27 °C - closed cup
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Tetramethylsilane in synthesis: selective mono-and polymethylations of germanium tetrachloride
Bordeau M, et al.
Organometallics, 1087-1089, 4-4 (1985)
Exhaustive One-Step Bridgehead Methylation of Adamantane Derivatives with Tetramethylsilane
Bonsir M, et al.
European Journal of Organic Chemistry, 2021, 5227-5237 (2021)
Jung Chao et al.
Frontiers in pharmacology, 11, 606759-606759 (2021-03-02)
Gallic acid (GA) is a simple polyphenol found in food and traditional Chinese medicine. Here, we determined the effects of GA administration in a combined mouse model of high-fat diet (HFD)-induced obesity and low-dose streptozotocin (STZ)-induced hyperglycemia, which mimics the
A novel approach to selecting thermomorphic multicomponent solvent systems (TMS) for hydroaminomethylation reactions
Behr A, et al.
Chemical Engineering and Processing, 69, 15-23 (2013)
Synthesis of alpha-SiC from tetramethylsilane by chemical vapor deposition at high temperature
Jeong S, et al.
Applied Physics Express, 7, 025501-025501 (2014)
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