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Merck

216593

Ammonium hexafluorophosphate

99.98% trace metals basis

Synonym(s):

Azanium hexafluorophosphate

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About This Item

Linear Formula:
NH4PF6
CAS Number:
Molecular Weight:
163.00
PubChem Substance ID:
eCl@ss:
38070413
UNSPSC Code:
12352302
NACRES:
NA.23
EC Number:
241-009-1
MDL number:
Assay:
99.98% trace metals basis
Form:
crystalline
Solubility:
acetic acid: slightly soluble(lit.), ethanol: slightly soluble(lit.), methanol: slightly soluble(lit.)
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assay

99.98% trace metals basis

form

crystalline

impurities

≤250.0 ppm Trace Metal Analysis

mp

58 °C (lit.)

solubility

acetic acid: slightly soluble(lit.), ethanol: slightly soluble(lit.), methanol: slightly soluble(lit.)

density

2.18 g/mL at 25 °C (lit.)

SMILES string

[H][N+]([H])([H])[H].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1

InChI key

NIZXKAYXSNUDOU-UHFFFAOYSA-O

General description

Ammonium hexafluorophosphate decomposes on heating before melting. Solubility of ammonium hexafluorophosphate in H2O at 20oC is 74.8% w/v. Additionally, it is very soluble in Me2CO, MeOH, EtOH and MeOAc, and is decomposed by boiling mineral acids.

Application

Ammonium hexafluorophosphate is used to synthesize polyethylene oxide based highly conductive non aqueous polymer gel electrolytes exhibiting high conductivity (>10-2S/cm at 25oC)


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Armarego WLF and Chai CLL
Purification of Laboratory Chemicals (2008)
Highly conductive non aqueous polymer gel electrolytes containing ammonium hexafluorophosphate (NH4PF6).
Sharma JP and Sekhon SS
J. Mater. Sci., 41(12), 3617-3622 (2006)
Masaru Yao et al.
Scientific reports, 5, 10962-10962 (2015-06-05)
Is it possible to exceed the lithium redox potential in electrochemical systems? It seems impossible to exceed the lithium potential because the redox potential of the elemental lithium is the lowest among all the elements, which contributes to the high