262072
Lanthanum(III) chloride heptahydrate
ACS reagent
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About This Item
Linear Formula:
LaCl3 · 7H2O
CAS Number:
Molecular Weight:
371.37
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
64.5-70.0% (ACS specification)
Grade:
ACS reagent
Form:
crystals
grade
ACS reagent
Quality Level
assay
64.5-70.0% (ACS specification)
form
crystals
reaction suitability
reagent type: catalyst
core: lanthanum
impurities
≤0.01% insolubles
mp
91 °C (dec.) (lit.)
cation traces
Ca: ≤0.001%, Mg: ≤0.001%
SMILES string
O.O.O.O.O.O.O.Cl[La](Cl)Cl
InChI
1S/3ClH.La.7H2O/h3*1H;;7*1H2/q;;;+3;;;;;;;/p-3
InChI key
FDFPDGIMPRFRJP-UHFFFAOYSA-K
General description
Lanthanum (III) chloride heptahydrate is a hydrated lanthanum salt. It can be used as a catalyst in organic synthesis as well as a mild Lewis acid. It is a cheap, readily available, and moisture-resistant catalyst.
Application
Lanthanum (III) chloride heptahydrate can be used as a catalyst:
- In the preparation of a series of 1H-indole-2,3-diones from anilines and oxalic acid under microwave-assisted solvent-free conditions.
- In the Knoevenagel condensation to preparation of substituted alkenes under solvent free condition.
- In the synthesis of highly functionalized piperidine derivatives by condensing 1,3-dicarbonyl compounds with aniline and aromatic aldehydes.
Biochem/physiol Actions
Calcium channel blocker
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signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1
flash_point_f
does not flash
flash_point_c
does not flash
Storage Class
11 - Combustible Solids
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Syntheses, characterization, and biocidal aspects of O, O'-ditolyl/dibenzyldithiophosphates of lanthanum (III) and their adducts with nitrogen and phosphorus donor bases.
Syed A and Pandey SK.
Monatshefte fur Chemie / Chemical Monthly, 144(8), 1129-1140 (2013)
Supramolecular assemblies with water-soluble p-sulfonatothiacalix [6] arene lanthanide complexes: one-dimensional 'ladder-type'coordination polymers and one-dimensional hydrogen-bonded polymers.
Yamada M and Hamada F.
CrystEngComm, 15(28), 5703-5712 (2013)
One-pot synthesis of 3, 4-dihydropyrimidin-2 (1H)-ones using lanthanum chloride as a catalyst.
Lu J, et al.
Tetrahedron Letters, 41(47), 9075-9078 (2000)