146617
Bathophenanthrolinedisulfonic acid disodium salt hydrate
98%
Synonym(s):
Bathophenanthrolinedisulfonic acid disodium salt trihydrate, 4,7-Diphenyl-1,10-phenanthroline-disulfonic acid disodium salt trihydrate, Disodium bathophenanthrolinedisulfonate trihydrate
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About This Item
Empirical Formula (Hill Notation):
C24H14N2Na2O6S2 · 3H2O
CAS Number:
Molecular Weight:
590.53
MDL number:
EC Number:
258-152-0
NACRES:
NA.22
UNSPSC Code:
12352100
Assay:
98%
Form:
powder
Quality Level
assay
98%
form
powder
reaction suitability
reagent type: ligand
reaction type: click chemistry
mp
300 °C
solubility
water: soluble 100 mg/mL, clear to slightly hazy, yellow (to red)
General description
Bathophenanthrolinedisulfonic acid disodium salt forms water soluble complexes with palladium and their catalytic role in oxidation of 2-hexanol has been examined.
Application
Bathophenanthrolinedisulfonic acid disodium salt hydrate was used in the preparation of anionic Europium(III) disulfonated bathophenanthroline tris(dibenzoylmethanate) complex.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Catalytic Conversions in Water. Part 23: Steric Effects and Increased Substrate Scope in the Palladium-Neocuproine Catalyzed Aerobic Oxidation of Alcohols in Aqueous Solvents#.
Brink GJ, et al.
Advanced Synthesis & Catalysis, 345(12), 1341-1352 (2003)
Intercalation of luminescent Europium (III) complexes in layered double hydroxides.
Sarakha L, et al.
Opt. Mater., 31(3), 562-566 (2009)
Elizabeth M Zammit et al.
The Analyst, 136(15), 3069-3072 (2011-06-29)
The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.