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Merck

703516

Zinc chloride solution

greener alternative

1.9 M in 2-methyltetrahydrofuran

Synonym(s):

Dichlorozinc

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About This Item

Linear Formula:
ZnCl2
CAS Number:
7646-85-7
Molecular Weight:
136.30
NACRES:
NA.23
PubChem Substance ID:
329762045
UNSPSC Code:
12352302
MDL number:
MFCD00011295
Form:
liquid

Key Documents

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InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

SMILES string

Cl[Zn]Cl

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

form

liquid

reaction suitability

core: zinc, reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

concentration

1.9 M in 2-methyltetrahydrofuran, 25 % (w/w)

density

1.07 g/mL at 25 °C

greener alternative category

, Aligned

Quality Level

100

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Lewis acid in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

10.4 °F - closed cup - Solvent

flash_point_c

-12 °C - closed cup - Solvent

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SHBT0090
SHBR7617
SHBS2984
SHBQ6222
SHBP7422

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Hai-Long Jiang et al.
Journal of the American Chemical Society, 134(36), 14690-14693 (2012-08-22)
Reactions of ZrCl(4) and single or mixed linear dicarboxylic acids bearing methyl or azide groups lead to highly stable isoreticular metal-organic frameworks (MOFs) with content-tunable, accessible, reactive azide groups inside the large pores. These Zr-based MOFs offer an ideal platform
Hatice Yorulmaz et al.
Biological trace element research, 151(2), 256-262 (2012-11-28)
We evaluated the effect of zinc treatment on the blood-brain barrier (BBB) permeability and the levels of zinc (Zn), natrium (Na), magnesium (Mg), and copper (Cu) in the brain tissue during epileptic seizures. The Wistar albino rats were divided into
Anne Müller et al.
PloS one, 8(1), e53347-e53347 (2013-01-22)
The G-protein coupled receptor 83 (GPR83) is an orphan G-protein coupled receptor for which the natural ligand(s) and signaling pathway(s) remain to be identified. Previous studies suggest a role of GPR83 in the regulation of thermogenesis and the control of
Anat Elmann et al.
Oxidative medicine and cellular longevity, 2012, 157598-157598 (2013-01-16)
Oxidative stress is involved in the pathogenesis of neurodegenerative diseases such as Parkinson's and Alzheimer's diseases. Astrocytes, the most abundant glial cells in the brain, protect neurons from reactive oxygen species (ROS) and provide them with trophic support, such as
Russell E Carter et al.
Journal of neurochemistry, 125(5), 673-684 (2013-03-19)
Spreading depolarization (SD) is a feed-forward wave that propagates slowly throughout brain tissue and recovery from SD involves substantial metabolic demand. Presynaptic Zn(2+) release and intracellular accumulation occurs with SD, and elevated intracellular Zn(2+) ([Zn(2+) ]i ) can impair cellular
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