74104
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride
≥97.0% (calc. on dry substance, AT), for peptide synthesis
Synonym(s):
DMTMM, MMTM
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About This Item
Empirical Formula (Hill Notation):
C10H17ClN4O3
CAS Number:
Molecular Weight:
276.72
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Beilstein/REAXYS Number:
8026872
Product Name
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride, 95% (HPLC)
Quality Level
assay
95% (HPLC)
form
powder
reaction suitability
reaction type: Coupling Reactions
impurities
≤17 wt. % water
application(s)
peptide synthesis
functional group
ether
storage temp.
−20°C
SMILES string
[Cl-].COc1nc(OC)nc(n1)[N+]2(C)CCOCC2
InChI
1S/C10H17N4O3.ClH/c1-14(4-6-17-7-5-14)8-11-9(15-2)13-10(12-8)16-3;/h4-7H2,1-3H3;1H/q+1;/p-1
InChI key
BMTZEAOGFDXDAD-UHFFFAOYSA-M
Application
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride can be used as a condensing agent for the following transformations:
- Condensation of carboxylic acids and amines to the corresponding amides in tetrahydrofuran.
- Esterification of carboxylic acids with alcohols to the corresponding esters.
- Conversion of carboxylic acids to the corresponding Weinreb amides in protic solvents.
Reagent for activating carboxylic acids in solution and solid phase peptide synthesis; superior or comparable to the most popular coupling reagents
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
flash_point_f
198.5 °F - closed cup
flash_point_c
92.5 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Chameen Samarawickrama et al.
Cornea, 37(5), 609-616 (2017-11-28)
To describe the use of collagen-based alternatives to cyanoacrylate glue for the sealing of acute corneal perforations. A collagen analog comprising a collagen-like peptide conjugated to polyethylene glycol (CLP-PEG) and its chemical crosslinker were tested for biocompatibility. These CLP-PEG hydrogels
Tetrahedron, 55, 13159-13159 (1999)
Esterification of carboxylic acids with alcohols by 4-(4, 6-dimethoxy-1, 3, 5-triazin-2-yl)-4-methyl-morpholinium chloride (DMTMM).
Kunishima M
Synlett, 1999(08), 1255-1256 (1999)