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Merck

407666

Ammonia solution

0.4 M in dioxane

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About This Item

Linear Formula:
NH3
CAS Number:
Molecular Weight:
17.03
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
Concentration:
0.4 M in dioxane, 450-600 mmol/L (titration)
Form:
liquid
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Quality Level

vapor pressure

11.73 psi ( 55 °C), 4.16 psi ( 20 °C)

form

liquid

concentration

0.4 M in dioxane, 450-600 mmol/L (titration)

density

1.023 g/mL at 25 °C

SMILES string

N

InChI

1S/H3N/h1H3

InChI key

QGZKDVFQNNGYKY-UHFFFAOYSA-N

General description

The product is a 0.4 M solution of ammonia in dioxane. Ammonia is a colorless gas with a characteristic strong odor. It is highly soluble in water, alcohol, chloroform and ether. It is extensively sold in the form of solution.1 Ammonia molecule is pyramidal in shape with nitrogen in the center and the three hydrogen atoms along the three vertices and the lone pair of electrons on the fourth vertex. Ammonia solution is commonly used as a base.

Application

Ammonia solution (0.4 M in dioxane) may be used in the synthesis of 8-nitroquinolin-2-amine and silphenylene-containing polymers.


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Danger

Hazard Classifications

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup



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Eagleson M.
Concise Encyclopedia Chemistry, 65-66 (1994)
Discovery of a new antileishmanial hit in 8-nitroquinoline series.
Paloque L, et al.
European Journal of Medicinal Chemistry, 54, 75-86 (2012)
Synthesis and properties of polymers containing silphenylene moiety via catalytic cross-dehydrocoupling polymerization of 1,4-bis (dimethylsilyl) benzene.
Li Y and Kawakami Y.
Macromolecules, 32(26), 8768-8773 (1999)