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Merck

450995

Manganese(II) chloride

AnhydroBeads, −10 mesh, 99.999% trace metals basis

Synonym(s):

Manganese dichloride, Sacchite

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About This Item

Linear Formula:
MnCl2
CAS Number:
Molecular Weight:
125.84
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
99.999% trace metals basis
Grade:
synthesis grade
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Product Name

Manganese(II) chloride, AnhydroBeads, −10 mesh, 99.999% trace metals basis

InChI

1S/2ClH.Mn/h2*1H;/q;;+2/p-2

SMILES string

Cl[Mn]Cl

InChI key

GLFNIEUTAYBVOC-UHFFFAOYSA-L

grade

synthesis grade

product line

AnhydroBeads

assay

99.999% trace metals basis

reaction suitability

core: manganese

impurities

≤15.0 ppm Trace Metal Analysis

particle size

−10 mesh

mp

652 °C (lit.)

density

2.98 g/mL at 25 °C (lit.)

application(s)

battery precursors
catalysts
electroplating
material synthesis precursor

Quality Level

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Application

A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state. Also used in the formation of an active Mn(0) species useful for radical cyclization reactions.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2

target_organs

Brain

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Abbati, G.L. et al.
Inorganic Chemistry, 37, 1430-1430 (1998)
Tang, J. et al.
Tetrahedron, 55, 1893-1893 (1999)
Asad A Aboud et al.
Neurotoxicology, 33(6), 1443-1449 (2012-10-27)
Manganese (Mn) is an environmental risk factor for Parkinson's disease (PD). Recessive inheritance of PARK2 mutations is strongly associated with early onset PD (EOPD). It is widely assumed that the influence of PD environmental risk factors may be enhanced by
M R Sepúlveda et al.
Contrast media & molecular imaging, 7(4), 426-434 (2012-06-01)
Manganese is a vital element and cofactor of many key enzymes, but it is toxic at high levels, causing pronounced disturbances in the mammalian brain. Magnetic resonance imaging (MRI) studies using manganese ions as a paramagnetic contrast agent are often
Elizabeth Greally et al.
Journal of cardiovascular magnetic resonance : official journal of the Society for Cardiovascular Magnetic Resonance, 15, 4-4 (2013-01-18)
Manganese-enhanced cardiovascular magnetic resonance (MECMR) can non-invasively assess myocardial calcium influx, and calcium levels are known to be elevated in muscular dystrophy cardiomyopathy based on cellular studies. Left ventricular functional studies and MECMR were performed in mdx mice (model of

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