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Merck

BCR270

Triphenylene

BCR®, certified reference material

Synonym(s):

9,10-Benzophenanthrene

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About This Item

Empirical Formula (Hill Notation):
C18H12
CAS Number:
217-59-4
Molecular Weight:
228.29
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329773803
EC Number:
205-922-9
Beilstein/REAXYS Number:
1342908
MDL number:
MFCD00001108

Key Documents

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Product Name

Triphenylene, BCR®, certified reference material

InChI key

SLGBZMMZGDRARJ-UHFFFAOYSA-N

InChI

1S/C18H12/c1-2-8-14-13(7-1)15-9-3-4-11-17(15)18-12-6-5-10-16(14)18/h1-12H

SMILES string

c1ccc2c(c1)c3ccccc3c4ccccc24

grade

certified reference material

agency

BCR®

manufacturer/tradename

JRC

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

bp

438 °C (lit.)

mp

195-198 °C (lit.)

format

neat

storage temp.

2-8°C

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Analysis Note

For more information please see:
BCR270

Legal Information

BCR is a registered trademark of European Commission

pictograms

CorrosionEnvironment
GHS05,GHS09

signalword

Danger

hcodes

H318,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Fabián Vaca Chávez et al.
The journal of physical chemistry. B, 116(8), 2339-2346 (2012-02-23)
The Larmor frequency and temperature dependence of the proton nuclear magnetic resonance (NMR) spin-lattice relaxation time was measured in the isotropic and columnar phases of both chain-end fluorinated triphenylene disk-like and fully hydrogenated molecules. In the columnar phase, the results
Jeongho Jay Lee et al.
Angewandte Chemie (International ed. in English), 51(34), 8490-8494 (2012-07-24)
Orient and conduct: Triphenylene-based discotic ionic liquid crystals (ILCs) with six imidazolium ion pendants can disperse pristine single-walled carbon nanotubes (SWNTs). When the ILC is columnarly assembled, doping with SWNTs results in macroscopic homeotropic columnar orientation. Combination of shear and
Lin Jiang et al.
Organic letters, 13(12), 3020-3023 (2011-05-25)
Triphenylene has been successfully fused to the porphyrin periphery through a convenient oxidative ring-closure reaction. Bistriphenylene-fused porphyrins and a dibenzo[fg,op]tetracene-fused porphyrin have also been obtained using a similar approach. These π-extended porphyrins exhibited broadened and bathochromic shifted UV-vis absorptions.
Wide-range 2D lattice correlation unveiled for columnarly assembled triphenylene hexacarboxylic esters.
Terutsune Osawa et al.
Angewandte Chemie (International ed. in English), 51(32), 7990-7993 (2012-07-04)
Vandana Bhalla et al.
Langmuir : the ACS journal of surfaces and colloids, 27(24), 15275-15281 (2011-11-15)
Triphenylene-based discotic liquid crystal 3 bearing 1,2,3-triazole groups has been synthesized using "click" chemistry. Discotic mesogen 3 has good thermal stability, and incorporation of triazole groups results in stabilization of columnar mesophases down to room temperature and formation of organogels
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