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Merck

06203

Sodium hydroxide

puriss., meets analytical specification of Ph. Eur., BP, NF, E524, 98-100.5%, pellets

Synonym(s):

‘Caustic soda’

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About This Item

Linear Formula:
NaOH
CAS Number:
Molecular Weight:
40.00
PubChem Substance ID:
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
215-185-5
MDL number:
assay:
98-100.5%
vapor pressure:
<18 mmHg ( 20 °C)
3 mmHg ( 37 °C)

Product Name

Sodium hydroxide, puriss., meets analytical specification of Ph. Eur., BP, NF, E524, 98-100.5%, pellets

SMILES string

[OH-].[Na+]
[OH-].[Na+]

InChI key

HEMHJVSKTPXQMS-UHFFFAOYSA-M

InChI

1S/Na.H2O/h;1H2/q+1;/p-1

vapor density

>1 (vs air)

vapor pressure

<18 mmHg ( 20 °C)
3 mmHg ( 37 °C)

grade

puriss.

assay

98-100.5%

form

pellets

quality

meets analytical specification of Ph. Eur., BP, NF, E524

impurities

≤0.0005% total nitrogen (N)
≤0.002% heavy metals (as Pb)
≤0.5% Na2CO3

mp

318 °C (lit.)

solubility

water: soluble 1260 g/L at 20 °C

density

2.13 g/cm3 at 20 °C

anion traces

chloride (Cl-): ≤20 mg/kg
phosphate (PO43-): ≤10 mg/kg
silicate (as SiO2): ≤100 mg/kg
sulfate (SO42-): ≤30 mg/kg

cation traces

Al: ≤10 mg/kg
As: ≤2 mg/kg
Ca: ≤10 mg/kg
Fe: ≤10 mg/kg
Hg: ≤1 mg/kg
K: ≤1000 mg/kg
Pb: ≤0.5 mg/kg

Quality Level

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Application

Sodium hydroxide can be used as:
  • A reagent in the gold-catalyzed selective oxidation of glycerol to glyceric acid.
  • A catalyst for the cross-dehydrogenative coupling of alcohols and hydrosilanes to synthesize silyl ethers.
  • A base in the transition-metal free Sonogashira-type couplings of aryl halides and alkynes to synthesize ynones in the presence of PEG as a phase-transfer agent.

General description

Sodium hydroxide, also known as lye and caustic soda, is a strong base used universally as a neutralization agent in the chemical industry, paper making, petroleum refining, cleaning compounds, and drain cleaners.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Chemoselective, solvent-free aldol condensation reaction.
Raston CL and Scott JL.
Green Chemistry, 2(2), 49-52 (2000)
Kinetics of sodium borohydride direct oxidation and oxygen reduction in sodium hydroxide electrolyte: Part I. BH4- electro-oxidation on Au and Ag catalysts.
Chatenet M, et al.
Electrochimica Acta, 51(25), 5459-5467 (2006)
M A Roberts et al.
Analytical chemistry, 69(11), 2035-2042 (1997-06-01)
This report describes a UV laser photoablation method for the production of miniaturized liquid-handling systems on polymer substrate chips. The fabrication of fluid channel and reservoir networks is accomplished by firing 200 mJ pulses from an UV excimer laser at
Silvio Carrettin et al.
Chemical communications (Cambridge, England), (7)(7), 696-697 (2002-07-18)
Glycerol is oxidised to glyceric acid with 100% selectivity using either 1% Au/charcoal or 1% Au/graphite catalyst under mild reaction conditions (60 degrees C, 3 h, water as solvent).
Determination of specific surface area of colloidal silica by titration with sodium hydroxide.
Sears Jr GW.
Analytical Chemistry, 28(12), 1981-1983 (1956)

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