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Merck

8.03945

Iron(III) chloride

greener alternative

anhydrous for synthesis

Sinónimos:

Iron(III) chloride, Ferric chloride, Iron trichloride

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About This Item

Fórmula empírica (notación de Hill):
Cl3Fe
Número CAS:
7705-08-0
Peso molecular:
162.20
UNSPSC Code:
12352302
EC Index Number:
231-729-4
NACRES:
NA.22
MDL number:
MFCD00011005
grade:
synthesis grade
form:
powder
solubility:
920 g/L (Hydrolysis)

Nombre del producto

Iron(III) chloride, anhydrous for synthesis

SMILES string

[Fe](Cl)(Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

grade

synthesis grade

vapor pressure

1 hPa ( 20 °C)

form

powder

potency

316 mg/kg LD50, oral (Rat)

greener alternative product characteristics

Catalysis
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pH

1 (20 °C, 200 g/L in H2O)

mp

306 °C (decomposition)

solubility

920 g/L (Hydrolysis)

density

2.89 g/cm3 at 25 °C

bulk density

1000 kg/m3

greener alternative category

, Aligned

storage temp.

2-30°C

Quality Level

200

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Analysis Note

Assay (iodometric): ≥ 98.0 %
Identity (Fe): passes test
Identity (Cl): passes test

Application

Iron(III) chloride (FeCl3) can be used as a catalyst:
  • For the oxidation of glucose to gluconic acid in water.
  • To synthesize 2-iodo substituted benzo[b]thiophenes by iodocyclization of 2-alkynylthioanisoles in the presence of sodium iodide and ethanol as a solvent.
  • In the glycosylation sugars in the presence of allyl and alkynyl alcohols to synthesize corresponding glycosides.
  • To prepare 1,2-trans glycosyl azides by azido glycosylation of glycosyl β-peracetates.

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1

Clase de almacenamiento

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Green synthesis of benzo [b] thiophenes via iron (III) mediated 5-endo-dig iodocyclization of 2-alkynylthioanisoles
Kesharwani T, et al.
Tetrahedron Letters, 57(3), 411-414 (2016)
Iron (III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
Narayanaperumal S, et al.
Journal of the Brazilian Chemical Society, 23, 1982-1988 (2012)
Santosh B Salunke et al.
Chemical communications (Cambridge, England), 47(37), 10440-10442 (2011-08-16)
A highly efficient and mild method for azido glycosylation of glycosyl β-peracetates to 1,2-trans glycosyl azides was developed by using inexpensive FeCl(3) as the catalyst. In addition, we demonstrated, for the first time, that FeCl(3) in combination with copper powder
Oxidative conversion of glucose to gluconic acid by iron (III) chloride in water under mild conditions
Zhang H, et al.
Green Chemistry, 18(8), 2308-2312 (2016)

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