P24101

Diphenyl ether

Name: Diphenyl ether
Brand: SIAL

99%, crystals, ReagentPlus^®

Sinónimos:

Diphenyl oxide, Phenyl ether

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About This Item

Fórmula lineal:

(C₆H₅)₂O

Número CAS:

101-84-8

Peso molecular:

170.21

NACRES:

NA.21

PubChem Substance ID:

57654511

UNSPSC Code:

12352100

EC Number:

202-981-2

MDL number:

MFCD00003034

Beilstein/REAXYS Number:

1364620

Nombre del producto

Diphenyl ether, ReagentPlus^®, 99%

InChI key

USIUVYZYUHIAEV-UHFFFAOYSA-N

InChI

1S/C12H10O/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H

SMILES string

O(c1ccccc1)c2ccccc2

vapor density

>5.86 (25 °C, vs air)

vapor pressure

<1 mmHg ( 20 °C)

product line

ReagentPlus^®

assay

99%

form

crystals

autoignition temp.

1144 °F

expl. lim.

1.5 %

refractive index

n20/D 1.579 (lit.)

bp

259 °C (lit.)

mp

25-27 °C (lit.)

density

1.073 g/mL at 25 °C (lit.)

functional group

phenoxy

Quality Level

200

Gene Information

human ... TTR(7276)

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Categorías relacionadas

Chemical Building Blocks

Organic Building Blocks

Application

Diphenyl ether may be used to synthesize dibenzofuran via intramolecular cyclization in the presence of palladium acetate.

General description

Diphenyl ether (DPE) is a bridged-phenyl molecule. The conformational analysis of using resonance-enhanced two-photon ionization method DPE has been reported.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

GHS07,GHS09

signalword

Warning

hcodes

H319,H410

pcodes

P264 - P273 - P280 - P305 + P351 + P338 - P337 + P313 - P391

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2

Clase de almacenamiento

11 - Combustible Solids

wgk

WGK 2

flash_point_f

239.0 °F - closed cup

flash_point_c

115 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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A REMPI investigation of the minimum energy conformations of diphenyl ether.

Paiva ACS, et al.

International Journal of Mass Spectrometry, 221(2), 107-115 (2002)

Palladium-promoted cyclization of diphenyl ether, diphenylamine, and related compounds.

Akermark B, et al.

The Journal of Organic Chemistry, 40(9), 1365-1367 (1975)

Determinants of prenatal exposure to polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) in an urban population.

Julie B Herbstman et al.

Environmental health perspectives, 115(12), 1794-1800 (2007-12-19)

Recent studies have reported blood levels of polybrominated diphenyl ethers (PBDEs) in the U.S. population. Information about neonatal levels and about the relationship to polychlorinated biphenyls (PCBs) exposures is limited. The objective was to characterize levels and determinants of fetal

Formation of toxic species and precursors of PCDD/F in thermal decomposition of alpha-cypermethrin.

Sindra L Summoogum et al.

Chemosphere, 85(2), 143-150 (2011-07-09)

This article examines the thermal decomposition of alpha-cypermethrin, one of the most common pyrethroid pesticides. The objective was to identify its decomposition pathways and to gain an understanding into the formation of toxic species in the environment, including those that

Solvent effects on the hydrogenolysis of diphenyl ether with Raney nickel and their implications for the conversion of lignin.

Xingyu Wang et al.

ChemSusChem, 5(8), 1455-1466 (2012-05-03)

The conversion of lignin, the most recalcitrant of the biopolymers, is necessary for a carbon-efficient utilization of lignocellulosic materials. In this context, hydrogenolysis of lignin is a process receiving increasing attention. In this report, the solvent effects on the hydrogenolysis

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