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Merck

27225

Ácido acético

glacial, puriss., meets analytical specification of Ph. Eur., BP, USP, 99.8-100.5%

Sinónimos:

Ácido acético glacial

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About This Item

Fórmula lineal:
CH3CO2H
Número CAS:
Peso molecular:
60.05
UNSPSC Code:
12352106
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-580-7
Beilstein/REAXYS Number:
506007
MDL number:

Nombre del producto

Ácido acético, glacial, puriss., meets analytical specification of Ph. Eur., BP, USP, 99.8-100.5%

InChI key

QTBSBXVTEAMEQO-UHFFFAOYSA-N

InChI

1S/C2H4O2/c1-2(3)4/h1H3,(H,3,4)

SMILES string

[F2C(F2C)13F3C]C(O)=O

agency

meets purity specifications of USP (identity)

vapor density

2.07 (vs air)

grade

puriss.

assay

99.8-100.5%

form

liquid

autoignition temp.

800 °F

expl. lim.

16 %, 92 °F
4 %, 59 °F

technique(s)

mass spectrometry (MS): suitable

impurities

K2Cr2O7 red. substances, complies
residual solvents, complies
≤0.0002% heavy metals (as Pb)
≤0.005% non-volatile matter
≤0.01% KMnO4 red. matter (as HCOOH)

refractive index

n20/D 1.371 (lit.)

pH

2.5 (20 °C, 50 g/L)

bp

117-118 °C (lit.)

mp

16.2 °C (lit.)

transition temp

freezing point ≥15.6 °C

density

1.04 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤2 mg/kg
sulfate (SO42-): ≤5 mg/kg

cation traces

Al: ≤0.5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤2 mg/kg
Pb: ≤0.5 mg/kg
Zn: ≤5 mg/kg

suitability

corresponds for appearance

Quality Level

quality

meets analytical specification of Ph. Eur., BP, USP

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Categorías relacionadas

Application

Acetic acid is widely employed as solvent for various oxidation reactions. It may be used in the analysis of synthetic peptides by electron transfer dissociation (ETD) tandem mass spectrometry (MS/MS). It may be used in the preparation of peroxyacetic acid (disinfectant), via reaction with perhydrol (30% hydrogen peroxide).

General description

Acetic acid is an organic carboxylic acid. It is a hygroscopic liquid having pungent odor. Its anhydrous form is commonly referred as glacial acetic acid. It forms dimers linked by hydrogen bonds in solution and gaseous phases. It is weakly acidic in nature.

Other Notes

The article number 27225-4X2.5L-M will be discontinued. Please order the single bottle 27225-2.5L-M which is physically identical with the same exact specifications.
The article number 27225-4X2.5L-R will be discontinued. Please order the single bottle 27225-2.5L-R which is physically identical with the same exact specifications.
The article number 27225-6X1L-M will be discontinued. Please order the single bottle 27225-1L-M which is physically identical with the same exact specifications.
The article number 27225-6X1L-R will be discontinued. Please order the single bottle 27225-1L-R which is physically identical with the same exact specifications.

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

Clase de almacenamiento

3 - Flammable liquids

wgk

WGK 1

flash_point_f

102.2 °F - closed cup

flash_point_c

39 °C - closed cup


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John E P Syka et al.
Proceedings of the National Academy of Sciences of the United States of America, 101(26), 9528-9533 (2004-06-24)
Peptide sequence analysis using a combination of gas-phase ion/ion chemistry and tandem mass spectrometry (MS/MS) is demonstrated. Singly charged anthracene anions transfer an electron to multiply protonated peptides in a radio frequency quadrupole linear ion trap (QLT) and induce fragmentation
Eagleson M.
Concise Encyclopedia Chemistry, 5-5 (1994)
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American journal of physiology. Regulatory, integrative and comparative physiology, 308(2), R123-R130 (2014-11-21)
In healthy individuals, postexercise protein supplementation increases muscle protein anabolism. In patients with muscular dystrophies, aerobic exercise improves muscle function, but the effect of exercise on muscle protein balance is unknown. Therefore, we investigated 1) muscle protein balance before, during

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