220418
Aluminum isopropoxide
≥98%
Synonym(s):
AIP, Aluminum isopropylate, Aluminum triisopropoxide
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About This Item
Linear Formula:
Al[OCH(CH3)2]3
CAS Number:
Molecular Weight:
204.24
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
209-090-8
Beilstein/REAXYS Number:
3910275
MDL number:
Quality Level
assay
≥98%
form
solid
reaction suitability
core: aluminum, reagent type: catalyst
mp
128-133 °C (lit.)
density
1.035 g/mL at 25 °C (lit.)
SMILES string
CC(C)O[Al](OC(C)C)OC(C)C
InChI
1S/3C3H7O.Al/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
InChI key
SMZOGRDCAXLAAR-UHFFFAOYSA-N
General description
Aluminum isopropoxide is a versatile andinexpensive Lewis acid catalyst and dehydrating agent widely used in the fieldof organic transformations, sol-gel processing, and rechargeable batteries.
Application
Aluminum isopropoxide can be used:
- As a precursor to synthesize alumina nanoparticles and multimetallic oxides via sol-gel processing.
- As a catalyst for various organic transformations such as Meerwein–Ponndorf–Verley–Oppenauer (MPVO) reactions and ring-opening polymerization of lactides and lactones.
- As coating material to fabricate electrodes for lithium-ion batteries toenhance cycling stability and performance.
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signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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Jiancong Liu et al.
Science advances, 3(5), e1603171-e1603171 (2017-06-01)
Thermally activated delayed fluorescence (TADF) materials are inspiring intensive research in optoelectronic applications. To date, most of the TADF materials are limited to metal-organic complexes and organic molecules with lifetimes of several microseconds/milliseconds that are sensitive to oxygen. We report
Enhanced cathode performance:Mixed Al2O3 and LiAlO2 coating of Li1.2Ni0.13Co0.13Mn0.54O2
Shengde Dong, et al.
ACS Applied Materials & Interfaces, 12, 38153-38162 (2020)
Activity and stability studies of H-transfer reduction reactions of aldehydes and ketones over aluminium isopropoxide heterogenised catalysts
Atika Muhammad, et al.
Royal Society of Chemistry Advances, 12, 33970-33980 (2022)