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Merck

106399

1-Adamantanecarboxylic acid

99%

Synonym(s):

Adamantane carboxylic acid

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About This Item

Empirical Formula (Hill Notation):
C11H16O2
CAS Number:
Molecular Weight:
180.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-584-6
Beilstein/REAXYS Number:
1910637
MDL number:
Assay:
99%
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InChI key

JIMXXGFJRDUSRO-KJZNFTALSA-N

InChI

1S/C11H16O2/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2,(H,12,13)/t7-,8+,9-,11-

SMILES string

OC(=O)C12C[C@H]3C[C@H](C[C@H](C3)C1)C2

assay

99%

Quality Level

mp

172-174 °C (lit.)

functional group

carboxylic acid

Application

1-Adamantanecarboxylic acid can be used as:
  • A stabilizer in the synthesis of monodisperse, highly crystalline CoPt3 nanoparticles and porous platinum nanoparticles.
  • An additive in polycondensation reactions to yield conjugated polymers as possible optoelectronic materials.
  • An additive in the allylic substitution reaction, which is catalyzed by palladium in an aqueous medium.

Biochem/physiol Actions

1-Adamantanecarboxylic acid undergoes complexation reactions with cyclohexaamylose. It is an inhibitor of phenyl ester hydrolysis of cycloheptaamylose.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Masaki Nakahata et al.
Nature communications, 2, 511-511 (2011-10-27)
Expanding the useful lifespan of materials is becoming highly desirable, and self-healing and self-repairing materials may become valuable commodities. The formation of supramolecular materials through host-guest interactions is a powerful method to create non-conventional materials. Here we report the formation
Thomas Le Saux et al.
Electrophoresis, 26(16), 3094-3104 (2005-07-26)
Among the different experimental strategies available in capillary electrophoresis (CE) to determine binding parameters, affinity capillary electrophoresis (ACE) has been the most widely embraced due to its easiness of implementation and of data handling. Ligand-substrate binding constants are thus directly
Detailed optimization of polycondensation reaction via direct C-H arylation of ethylenedioxythiophene
Yamazaki K, et al.
Macromolecular Rapid Communications, 34(1), 69-73 (2013)
Birgit Hakkarainen et al.
Carbohydrate research, 340(8), 1539-1545 (2005-05-12)
The hydrogen-bond network in mono-altro-beta-cyclodextrin and in its inclusion complex with adamantane-1-carboxylic acid were investigated by (1)H NMR spectroscopy using the chemical shifts, temperature coefficients and vicinal coupling constants of the exchangeable hydroxy protons. The chemical shifts of the 3-OH
Ronit Freeman et al.
Nano letters, 9(5), 2073-2076 (2009-04-10)
Beta-cyclodextrin (beta-CD)-functionalized CdSe/ZnS quantum dots (QDs) are used for optical sensing and chiroselective sensing of different substrates using a fluorescence resonance energy transfer (FRET) or an electron transfer (ET) mechanisms. The FRET between the QDs and Rhodamine B incorporated in

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