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Merck

221260

Ammonium iron(III) sulfate dodecahydrate

ACS reagent, 99%

Synonym(s):

Ammonium ferric sulfate dodecahydrate

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About This Item

Linear Formula:
NH4Fe(SO4)2 · 12H2O
CAS Number:
Molecular Weight:
482.19
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-382-4
MDL number:
Assay:
98.5-102.0% (ACS specification), 99%
Grade:
ACS reagent
Form:
crystals
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grade

ACS reagent

Quality Level

assay

98.5-102.0% (ACS specification), 99%

form

crystals

reaction suitability

reagent type: catalyst
core: iron

impurities

≤0.01% insolubles, ≤0.05% not NH4OH pptd.

pH

1 (25 °C, 482.2 g/L)

mp

39-41 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%, nitrate (NO3-): ≤0.01%

cation traces

Cu: ≤0.003%, Fe2+:, passes test (limit about 0.001%), Zn: ≤0.003%

storage temp.

2-8°C

SMILES string

N.O.O.O.O.O.O.O.O.O.O.O.O.[Fe+3].OS([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Fe.H3N.2H2O4S.12H2O/c;;2*1-5(2,3)4;;;;;;;;;;;;/h;1H3;2*(H2,1,2,3,4);12*1H2/q+3;;;;;;;;;;;;;;;/p-3

InChI key

LCPUDZUWZDSKMX-UHFFFAOYSA-K

Application

Ammonium ferric sulfate dodecahydrate may be used as a catalyst to synthesize:
  • Isoamyl acetate from acetic acid and isoamyl alcohol.
  • 2-Amino-5-(5-nitro-2-thienyl)-1,3,4-thiadiazole from 5-nitrothiophene-2-carboxaldehyde thiosemicarbazone via oxidative cyclization.


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Contemporary Chemical Industry null
Antituberculosis agents VIII: Synthesis and in vitro antimycobacterial activity of alkyl a-[5-(5-nitro-2-thienyl)-1, 3, 4-thiadiazole-2-ylthio] acetates.
Foroumadi A, et al.
Il Farmaco (Societa Chimica Italiana : 1989), 58(11), 1073-1076 (2003)
Mossbauer-Effect Study of the Ferroelectric Transitions in Potassium Ferrocyanide Trihydrate and Ferric Ammonium Sulfate Dodecahydrate.
Gleason TG and Walker JC.
Physical Review, 188(2), 893-893 (1969)