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Merck

253898

tert-Butyl ethyl ether

99%

Synonym(s):

2-Ethoxy-2-methylpropane, Ethyl tert-butyl ether, Ethyl tert-butyl oxide

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About This Item

Linear Formula:
C2H5OC(CH3)3
CAS Number:
Molecular Weight:
102.17
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39021026
UNSPSC Code:
12352100
EC Number:
211-309-7
MDL number:
Beilstein/REAXYS Number:
1731469
Assay:
99%
Form:
liquid
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InChI

1S/C6H14O/c1-5-7-6(2,3)4/h5H2,1-4H3

InChI key

NUMQCACRALPSHD-UHFFFAOYSA-N

SMILES string

CCOC(C)(C)C

vapor pressure

155 mmHg ( 25 °C)

assay

99%

form

liquid

refractive index

n20/D 1.375 (lit.)

bp

72-73 °C (lit.)

mp

−97 °C (lit.)

solubility

water: soluble 1.2 g/100g at 20 °C(lit.)

density

0.742 g/mL at 25 °C (lit.)

functional group

ether

Quality Level

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General description

Solid-phase microextraction of tert-butyl ethyl ether in human urine by using single-walled carbon nanotubes as adsorbent has been reported.

Application

tert-Butyl ethyl ether has been used as gasoline oxygenate and its biodegradation by propane-oxidizing bacteria has been studied.

pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-2.2 °F - closed cup

flash_point_c

-19 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Axel Müller et al.
Environmental pollution (Barking, Essex : 1987), 240, 639-646 (2018-05-18)
Microplastics are increasingly entering marine, limnic and terrestrial ecosystems worldwide, where they sorb hydrophobic organic contaminants. Here, the sorption behavior of the fuel-related water contaminants benzene, toluene, ethyl benzene and xylene (BTEX) and four tertiary butyl ethers to virgin and
Q Li et al.
International journal of immunopathology and pharmacology, 24(4), 837-847 (2012-01-11)
Ethyl tertiary-butyl ether (ETBE) is a motor fuel oxygenate used in reformulated gasoline. The current use of ETBE in gasoline or petrol is modest but increasing. To investigate the effects of ETBE on splenocytes, mice were exposed to 0 (control)
Marcy I Banton et al.
Journal of immunotoxicology, 8(4), 298-304 (2011-08-11)
The potential for immunotoxicological effects of ethyl tertiary butyl ether (ETBE, CAS RN 637-92-3) was studied in young adult female Crl:CD(SD) rats following subchronic oral exposures. Rats were exposed by gavage once daily for 28 consecutive days to 0, 250
Annemarie van Wezel et al.
Chemosphere, 76(5), 672-676 (2009-05-30)
The use of ETBE (ethyl-tert-butylether) as gasoline additive has recently grown rapidly. Contamination of aquatic systems is well documented for MTBE (methyl-tert-butylether), but less for other gasoline additives. Due to their mobility they may easily reach drinking water collection areas.
Françoise Fayolle-Guichard et al.
Journal of hazardous materials, 201-202, 236-243 (2011-12-20)
Ethyl tert-butyl ether (ETBE) was detected at high concentration (300mgL(-1)) in the groundwater below a gas-station. No significant carbon neither hydrogen isotopic fractionation of ETBE was detected along the plume. ETBE and BTEX biodegradation capacities of the indigenous microflora Pz1-ETBE

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