324868
Potassium trimethylsilanolate
90%, technical grade
Synonym(s):
Trimethylsilanol potassium salt
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Linear Formula:
(CH3)3SiOK
CAS Number:
Molecular Weight:
128.29
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.22
EC Number:
234-062-7
MDL number:
Beilstein/REAXYS Number:
3560282
Assay:
90%
Concentration:
≤100%
Form:
powder
Grade:
technical grade
grade
technical grade
assay
90%
form
powder
concentration
≤100%
mp
135-138 °C (lit.), 135-138 °C
Quality Level
Related Categories
Application
Potassium trimethylsilanolate can be used as a reagent in the:
It can also be used as a coupling promoter in cross-coupling reaction of aliphatic alkynylsilanols with aryl iodides.
- Hydrolysis of nitriles to primary amides.
- Conversion of esters to carboxylic acids, and dialkyl phosphonates to their monoalkyl phosphonates.
- Synthesis of E-alkenes, and nitrocefin.
It can also be used as a coupling promoter in cross-coupling reaction of aliphatic alkynylsilanols with aryl iodides.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Cross-coupling of alkynylsilanols with aryl halides promoted by potassium trimethylsilanolate
Denmark SE and Tymonko SA
The Journal of Organic Chemistry, 68(23), 9151-9154 (2003)
Tetrahedron Letters, 25, 5831-5831 (1984)
A practical synthesis of nitrocefin
Lee M, et al.
The Journal of Organic Chemistry, 70(1), 367-369 (2005)
Potassium trimethylsilanolate-mediated conversion of dialkyl phosphonates to their anhydrous potassium monoalkyl phosphonates under mild, non-aqueous conditions
Dziemidowicz J, et al.
Synthesis, 2005(04), 569-574 (2005)
Scope and limitations of sodium and potassium trimethylsilanolate as reagents for conversion of esters to carboxylic acids
Lovric M, et al.
Croatica Chemica Acta. Arhiv Za Kemiju, 80(1), 109-115 (2007)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service