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Merck

433632

Hydrazine solution

1.0 M in THF

Synonym(s):

Hydrazine, Nitrogen hydride

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About This Item

Linear Formula:
NH2NH2
CAS Number:
302-01-2
Molecular Weight:
32.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24867151
MDL number:
MFCD00011417
Beilstein/REAXYS Number:
878137
Form:
liquid

Key Documents

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InChI

1S/H4N2/c1-2/h1-2H2

SMILES string

NN

InChI key

OAKJQQAXSVQMHS-UHFFFAOYSA-N

form

liquid

concentration

1.0 M in THF

bp

65 °C

density

0.886 g/mL at 25 °C

functional group

hydrazine

Quality Level

100

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General description

Hydrazine promotes the cation exchange reaction for fast doping Cu ions into ZnSe nanocrystals.

Application

Hydrazine solution may be employed for the following studies:
  • As reducing agent for the reduction of the first row (3d) transition metal complexes in aqueous solution.
  • Preparation of nanoscale reduced metal oxides such as VO2(B), Cr2O3.
  • As fuel for the direct hydrazine fuel cell (DHFC).
  • As reducing agent for the synthesis of metallic monodisperse copper nanoparticles.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

ppe

Faceshields, Gloves, Goggles

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

302-01-2

CAS No.

302-01-2

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ4064
SHBR0073
SHBN6727
SHBM3098
SHBK8617

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Haibao Shao et al.
Journal of fluorescence, 25(2), 305-310 (2015-01-22)
Controllable doping is an effective way of tuning the properties of semiconductor nanocrystals (NCs). In this work, a simple strategy of fast doping Cu ions into ZnSe NCs under ambient conditions was proposed. The principle of doping is based on
Synthesis and characterization of reduced transition metal oxides and nanophase metals with hydrazine in aqueous solution.
Gui Z, et al.
Materials Research Bulletin, 38(1), 169-176 (2003)
Effects of NaOH addition on performance of the direct hydrazine fuel cell.
Yin WX, et al.
Journal of Power Sources, 182(2), 520-523 (2008)
Tomasz Kruk et al.
Colloids and surfaces. B, Biointerfaces, 128, 17-22 (2015-02-28)
Metallic monodisperse copper nanoparticles at a relatively high concentration (300 ppm CuNPs) have been synthesized by the reduction of copper salt with hydrazine in the aqueous SDS solution. The average particles size and the distribution size were characterized by Dynamic
M Vogel et al.
Fresenius' journal of analytical chemistry, 366(8), 781-791 (2001-03-03)
Hydrazine reagents are a well-known group of derivatizing agents for the determination of aldehydes and ketones in liquid and gaseous samples. Within this article, the most important hydrazine reagents are critically summarized, and their major applications in different fields, including
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