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Merck

673099

Biphenyl-4,4′-dithiol

95%

Synonym(s):

4,4′-Dimercaptobiphenyl, BDT, BPDT

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About This Item

Linear Formula:
HSC6H4C6H4SH
CAS Number:
Molecular Weight:
218.34
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
230-136-8
MDL number:
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Product Name

Biphenyl-4,4′-dithiol, 95%

Quality Level

InChI key

VRPKUXAKHIINGG-UHFFFAOYSA-N

InChI

1S/C12H10S2/c13-11-5-1-9(2-6-11)10-3-7-12(14)8-4-10/h1-8,13-14H

SMILES string

Sc1ccc(cc1)-c2ccc(S)cc2

assay

95%

form

solid

mp

165-174 °C

storage temp.

−20°C

Application

BPDT can be used to functionalize iron nanoparticles (NPs) with the gold shell (Fe−Au) on polyethylene substrate. It can also be coated on the p-doped gallium arsenic (GaAs) substrate for a variety of semiconductor applications.

General description

Biphenyl-4,4′-dithiol (BPDT) is an aryl dithiol that is prepared by taking a mixture of stannous chloride dihydrate and glacial acetic acid with anhydrous hydrogen chloride. It forms a self-assembled monolayer on a variety of surfaces by attaching one thiol group to the surface while the other can create nucleation sites for other functional groups.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 4

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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D Moser et al.
Scientific reports, 9(1), 11276-11276 (2019-08-04)
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Samuel S Haysom et al.
PloS one, 12(11), e0188411-e0188411 (2017-11-23)
To determine if a high-fat diet (HF) from weaning would result in a pro-inflammatory state and affect joint cartilage, we fed male rats either HF or Chow diet post-weaning, and voluntary wheel exercise (EX) or cage only activity (SED) after
Electrochemical, HR-XPS and SERS study of the self-assembly of biphenyl 4, 4′ -dithiol on Au (111) from solution phase.
Euti EM, et al.
Surface Science, 630(3), 101-108 (2014)
Brief Review of Surface Passivation on III-V Semiconductor.
Zhou L, et al.
Crystals, 8(5), 226-226 (2018)

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