940348
Dichloro(p-cymene)ruthenium(II) dimer ChemBeads
solid
Synonym(s):
(p-Cymene)ruthenium(II) chloride dimer ChemBeads, Benzene-1-methyl-4-(1-methylethyl)-ruthenium complex ChemBeads
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About This Item
Empirical Formula (Hill Notation):
C20H28Cl4Ru2
CAS Number:
Molecular Weight:
612.39
MDL number:
UNSPSC Code:
12352100
NACRES:
NA.21
Product Name
Dichloro(p-cymene)ruthenium(II) dimer ChemBeads,
SMILES string
Cc1ccc(C(C)C)cc1.CC(C)c2ccc(C)cc2.Cl[Ru]3[ClH][Ru](Cl)[ClH]3
InChI
InChI=1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key
LAXRNWSASWOFOT-UHFFFAOYSA-J
form
solid
composition
, 4-6 wt. % (loading)
reaction suitability
reagent type: catalyst
Quality Level
greener alternative product characteristics
Waste Prevention
Catalysis
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General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Greener Chemistry. ChemBeads are advanced solid-coated beads for high-throughput experimentation in various chemical applications. They enable precise dispensing of solid reagents, allowing researchers to conduct reactions with minimal material use, thus supporting waste prevention and catalysis principles while ensuring accuracy and reproducibility. This technology enhances efficiency and streamlines experimental processes in chemistry. Click here for more information.
The ChemBeads product of the (p-Cymene)ruthenium(II) chloride dimer. Loaded at 5% wt. on glass beads for use in high-throughput expermentation (HTE).
Dichloro(p-cymene)ruthenium(II) dimer is commonly used as a ruthenium starting material, and has been used in:
- Bifunctional P-containing RuO2 catalysts prepared from surplus Ru coordination complexes applied to Zn/Air batteries.
- The synthesis of half-sandwich type platinum-group metal complexes of C-glucosaminyl azines.
- The C(sp2)-H bond functionalization along with concomitant (4+2) annulation of coumarin-3-carboxamide.
-The acceptor engineering of ruthenium metallocycles with high phototoxic indices for safer photodynamic therapy.
Dichloro(p-cymene)ruthenium(II) dimer is commonly used as a ruthenium starting material, and has been used in:
- Bifunctional P-containing RuO2 catalysts prepared from surplus Ru coordination complexes applied to Zn/Air batteries.
- The synthesis of half-sandwich type platinum-group metal complexes of C-glucosaminyl azines.
- The C(sp2)-H bond functionalization along with concomitant (4+2) annulation of coumarin-3-carboxamide.
-The acceptor engineering of ruthenium metallocycles with high phototoxic indices for safer photodynamic therapy.
Features and Benefits
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Sebastián Lorca et al.
Nanomaterials (Basel, Switzerland), 13(1) (2023-01-09)
An innovative synthetic route that involves the thermal treatment of selected Ru co-ordination complexes was used to prepare RuO2-based materials with catalytic activity for oxygen reduction (ORR) and oxygen evolution (OER) reactions. Extensive characterization confirmed the presence of Ru metal
Anindita Sarkar et al.
Organic & biomolecular chemistry, 21(27), 5567-5586 (2023-06-26)
Efficacious protocols have been established to synthesize a structurally privileged Π-extended coumarin-fused pyridone nucleus by activating the vinylic C(sp2)-H bond of coumarin-3-carboxamide under the influence of inexpensive Ru(II)-metal. Here an N-methoxy carboxamide entity has been exploited as the chelating fragment
Chonglu Li et al.
Chemical science, 14(11), 2901-2909 (2023-03-21)
Although metallacycle-based photosensitizers have attracted increasing attention in biomedicine, their clinical application has been hindered by their inherent dark toxicity and unsatisfactory phototherapeutic efficiency. Herein, we employ a π-expansion strategy for ruthenium acceptors to develop a series of Ru(ii) metallacycles
Bryan T Ingoglia et al.
Tetrahedron, 75(32), 4199-4211 (2020-01-04)
Over the past three decades, Pd-catalyzed cross-coupling reactions have become a mainstay of organic synthesis. In particular, catalysts derived from biaryl monophosphines have shown wide utility in forming C-N bonds under mild reaction conditions. This work summarizes a variety of
Ana L Aguirre et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(51), 12981-12986 (2021-07-08)
High-throughput experimentation (HTE) methods are central to modern medicinal chemistry. While many HTE approaches to C-N and Csp2 -Csp2 bonds are available, options for Csp2 -Csp3 bonds are limited. We report here how the adaptation of nickel-catalyzed cross-electrophile coupling of
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