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Merck

132950

Chloroform

ReagentPlus®, ≥99.8%, contains 0.5-1.0% ethanol as stabilizer

Synonym(s):

Methylidyne trichloride, Trichloromethane

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About This Item

Empirical Formula (Hill Notation):
CHCl3
CAS Number:
67-66-3
Molecular Weight:
119.38
UNSPSC Code:
12191502
NACRES:
NA.04
PubChem Substance ID:
329750130
EC Number:
200-663-8
Beilstein/REAXYS Number:
1731042
MDL number:
MFCD00000826
Assay:
≥99.8%
Technique(s):
thin layer chromatography (TLC): suitable
Bp:
60.5-61.5 °C (lit.)
Vapor pressure:
160 mmHg ( 20 °C)

Key Documents

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InChI key

HEDRZPFGACZZDS-UHFFFAOYSA-N

InChI

1S/CHCl3/c2-1(3)4/h1H

SMILES string

ClC(Cl)Cl

vapor density

4.1 (vs air)

vapor pressure

160 mmHg ( 20 °C)

product line

ReagentPlus®

assay

≥99.8%

form

liquid

contains

0.5-1.0% ethanol as stabilizer

technique(s)

thin layer chromatography (TLC): suitable

impurities

≤0.03% (water)

color

APHA: ≤10

refractive index

n20/D 1.445 (lit.)

bp

60.5-61.5 °C (lit.)

mp

−63 °C (lit.)

density

1.48 g/mL at 25 °C, 1.492 g/mL at 25 °C (lit.)

Quality Level

100

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General description

The product is chloroform and it contains 0.5-1.0% ethanol as a stabilizer. Chloroform, a halogenated hydrocarbon, is widely employed as a solvent. Kinetics and mechanism of its photochemical degradation have been investigated in the presence of TiO2 aqueous suspensions (wavelength range of 310-380nm). Chloroform is a common groundwater pollutant. Its degradation by hydrodechlorination in the presence of Pd and Pd-Au catalysts and by dechlorination induced by glow discharge plasma (GDP) in contact with a sodium sulfate solution have been reported.

Application

Chloroform has been employed as a solvent for loading of pyocyanin on TLC (Thin Layer Chromatography) plate in a study. It can also be used as an extraction solvent in the determination of sodium dodecyl sulfate, via flow injection extraction method.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

target_organs

Liver,Kidney, Respiratory system

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

does not flash

flash_point_c

does not flash

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

67-66-3

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB6108
SDBB2733
SDBB1500
STBL3130
SHBQ4257

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Rajkumar Cheluvappa
MethodsX, 1, 67-73 (2014-01-01)
Preparation of the toxin pyocyanin from the bacterium Pseudomonas aeruginosa is an exacting procedure. Pyocyanin is expensive to commercially purchase. The sellers do not give out the extraction procedure. Classically, pyocyanin preparation involves complicated multi-step P. aeruginosa culturing and solvent
High activity and regenerability of a palladium-gold catalyst for chloroform degradation.
Velazquez JC, et al.
Journal of Chemical Technology and Biotechnology (2015)
Yongjun Liu et al.
Journal of hazardous materials, 308, 84-90 (2016-01-26)
In this study, efficient dechlorination and decomposition of chloroform (CF) induced by glow discharge plasma (GDP) in contact with a sodium sulfate solution was investigated. Intermediate byproducts were determined by ionic chromatography and headspace gas chromatography, respectively. Results showed that
Photolysis of chloroform and other organic molecules in aqueous titanium dioxide suspensions.
Kormann C, et al.
Environmental Science & Technology, 25(3), 494-500 (1991)
Analytical chemistry in a drop. Solvent extraction in a microdrop.
Liu H and Dasgupta PK.
Analytical Chemistry, 68(11), 1817-1821 (1996)
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